# US 6,294,871 B1 · Ultraviolet and visible filter for ceramic arc tube body

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- Number: US 6,294,871 B1
- Document ID: US6294871B1
- Status: Granted
- Kind: B1
- Application number: 09/235,647
- Filed: 1999-01-22
- Granted: 2001-09-25
- Earliest claimed: 1999-01-22
- Assignees: General Electric Company
- Inventors: Curtis E. Scott; H. Michael Laska; Mary Sue Kaliszewski; Csaba F. Rappensberger
- Web page: https://patentgrep.com/patent/US6294871B1

## CPC

- H01J 61/302: {characterised by the material of the vessel}
- H01J 61/827: {Metal halide arc lamps}
- H01J: ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS (spark-gaps H01T; electric arc lamps H05B31/00; particle accelerators H05H)

## Abstract

A ceramic arc tube for a metal halide discharge lamp is soaked in a dopant solution. The dopant solution includes a salt of a UV-absorbing additive, such as europium, cerium, or titanium. The salt is converted to the oxide form of the UV-absorbing additive during sintering of the arc tube. Lamps fabricated using the doped arc tubes filter UV from light emitted from the discharge without appreciably absorbing light in the visible range. The UV retained in the lamp causes the lamp to run at a hotter temperature, improving light output.

## Claims

### Claim 1

A UV-attenuating discharge vessel for an arc discharge lamp comprising:
an arc tube body which defines a discharge space for receiving a metal halide fill, the body being constructed from a ceramic material selected from the group consisting of polycrystalline metal oxides and monocrystalline metal oxides and being doped with a UV-attenuating additive which includes europium oxide.

### Claim 2

A UV-attenuating discharge vessel for an arc discharge lamp comprising:
an arc tube body which defines a discharge space for receiving, a metal halide fill the body being constructed from a ceramic material doped with a UV-attenuating additive, the UV-attenuating additive being at a concentration of less than about 5000 ppm.

### Claim 3 (depends on 2)

The vessel of claim 2, wherein the uv-attenuating additive is at a concentration of between about 500 and about 2500 ppm.

### Claim 4 (depends on 3)

The vessel of claim 3, wherein the uv-attenuating additive is europium oxide at a concentration of between about 1000 and about 1500 ppm.

### Claim 5

A UV-attenuating discharge vessel for an arc discharge lamp comprising:
an arc tube body which defines a discharge space for receiving a metal halide fill, the body constructed from a ceramic material selected from the group consisting of polycrystalline metal oxides and monocrystalline metal oxides and being doped with a UV attenuating additive, the arc tube body further comprising magnesia at a concentration of about 400-1500 ppm.

### Claim 6

A visible light transmissive, UV light attenuating metal halide lamp comprising:
an envelope;
a discharge vessel received in the envelope, the vessel including:
an arc tube body which defines a chamber, the body being constructed from a ceramic material doped with a UV-attenuating additive the UV-attenuating additive which includes an oxide of a lanthanide series element selected from the group consisting of lanthanum, cerium, europium, dysprosium, neodymium and combinations thereof;
electrodes extending into the chamber; and,
a fill sealed within the chamber, the fill including a metal halide for initiating and sustaining an arc discharge.

### Claim 7 (depends on 6)

The lamp of claim 6, wherein the UV-attenuating additive includes an europium oxide.

### Claim 8 (depends on 6)

The lamp of claim 6, wherein the UV-attenuating additive is at a concentration of less than about 5000 ppm.

### Claim 9 (depends on 8)

The lamp of claim 8, wherein the UV-attenuating additive is at a concentration of between about 500 and about 2500 ppm.

### Claim 10 (depends on 9)

The lamp of claim 9, wherein the UV-attenuating additive is europium oxide at a concentration of between about 1000 and about 1500 ppm.

### Claim 11 (depends on 6)

The lamp of claim 6, wherein the arc tube body filters at least about 70 percent of UV light emitted by the discharge.

### Claim 12 (depends on 6)

The lamp of claim 6, wherein the metal halide includes sodium iodide.

### Claim 13 (depends on 12)

The lamp of claim 12 wherein the fill further comprises mercury.

### Claim 14

A method of forming a UV-attenuating arc tube body for a metal halide discharge lamp, the method comprising:
forming a porous arc tube body from a mixture which includes powdered alumina;
infiltrating a dopant into the porous arc tube body, the dopant including a salt of a UV-absorbing additive; and
sintering the doped porous arc tube body at a sufficient temperature and for a sufficient time for the alumina to become substantially translucent and for the salt to be converted to the UV attenuating additive.

### Claim 15 (depends on 14)

The method of claim 14, wherein the step of infiltrating the dopant includes:
adding the dopant to a binder solution;
soaking at least a component of the porous arc tube body in the binder solution including the dopant;
evaporating water from the doped component of the porous arc tube body; and,
wherein the step of forming a porous arc tube body from a mixture which includes powdered alumina includes assembling the porous arc tube from at least the doped component.

### Claim 16 (depends on 14)

The method of claim 14, wherein the step of infiltrating the dopant includes:
heating the porous arc tube body to a temperature of at least about 1100° C. and then,
soaking the porous arc tube body in the dopant the ceramic material being selected from the group consisting of polycrystalline metal oxides and monocrystalline metal oxides.

### Claim 17

A UV-attenuating discharge vessel for an arc discharge lamp comprising:
an arc tube body which defines a discharge space for receiving a metal halide fill, the body being constructed from a ceramic material doped with a UV-attenuating additive, the UV-attenuating additive including an oxide of a lanthanide series element selected from the group consisting of cerium, europium, lanthanum, dysprosium, neodymium, and combinations thereof.

### Claim 18 (depends on 17)

The vessel of claim 17, wherein the UV-attenuating additive includes europium oxide.

### Claim 19

An arc tube body for an arc discharge lamp which defines a discharge space for receiving a metal halide fill, the body being constructed from a ceramic material doped with a UV-attenuating additive by a process which includes:
infiltrating a dopant solution into a porous arc tube body, the dopant solution including a compound which is convertible to the UV-absorbing additive; and
converting the compound to the UV-attenuating additive.

### Claim 20

A method of forming a UV-attenuating arc tube body for a metal halide discharge lamp, the method comprising:
forming a porous arc tube body which is permeable to a dopant solution;
infiltrating a dopant solution into the porous arc tube body, the dopant solution including a salt of a UV-absorbing additive; and
sintering the doped porous arc tube body at a sufficient temperature and for a sufficient time for the salt to be converted to the UV attenuating additive.
