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US 6,294,703 B1Granted
Process for the manufacture of cycloalkyldimethanol
AssigneeMitsubishi Chemical Corporation
InventorsYoshinori Hara, Koetsu Endou, Hiroko Takahashi
Life of this patent
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Abstract
A process for making cycloalkyldimethanol, includes hydrogenating at least one cycloalkyldicarboxylic acid and/or an alkyl ester thereof with a catalyst, to produce a cycloalkyldimethanol, where the catalyst contains ruthenium, tin and platinum. Also, a method for regenerating a used catalyst, includes contacting the used catalyst with a base, where the catalyst includes ruthenium, tin and platinum.
Claims18
A process for making cycloalkyldimethanol, comprising:
- hydrogenating at least one starting compound selected from the group consisting of cycloalkyldicarboxylic acid and an alkyl ester thereof with hydrogen in a liquid phase in the presence of a catalyst and 0.1 to 80% by weight, relative to the starting compound, of an alkali metal salt or an alkaline earth metal salt at a temperature of from 150-240° C., to produce said cycloalkyldimethanol;
- wherein said catalyst comprises ruthenium, tin and platinum.
A method for regenerating a used catalyst, comprising:
- hydrogenating at least one starting compound selected from the group consisting of cycloalkyldicarboxylic acid and an alkyl ester thereof with hydrogen in a liquid phase in the presence of a catalyst comprising ruthenium, tin and platinum and 0.1 to 80% by weight, relative to the starting compound, of an alkali metal salt or an alkaline earth metal salt at a temperature of from 150-240° C., to produce cycloalkyldimethanol;
- obtaining the used catalyst from said hydrogenation and contacting said used catalyst with a base to regenerate said used catalyst.
A method for making cycloalkyldimethanol, comprising:
- hydrogenating at least one starting compound selected from the group consisting of cycloalkyldicarboxylic acid and an alkyl ester thereof with hydrogen in a liquid phase in the presence of a catalyst comprising ruthenium, tin and platinum and 0.1 to 80% by weight, relative to the starting compound, of an alkali metal salt or an alkaline earth metal salt at a temperature of from 150-240° C., to produce cycloalkyldimethanol;
- obtaining the used catalyst from said hydrogenation and contacting said used catalyst with a base to regenerate said used catalyst;
- hydrogenating at least one starting compound selected from the group consisting of cycloalkyldicarboxylic acid and an alkyl ester thereof with hydrogen in a liquid phase in the presence of the regenerated used catalyst and 0.1 to 80% by weight, relative to the starting compound, of an alkali metal salt or an alkaline earth metal salt at a temperature of from 150-240° C., to produce cycloalkyldimethanol.
Dependencies are inferred from the claim text.