# US 6,294,601 B1 · Silica glass composition

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- Number: US 6,294,601 B1
- Document ID: US6294601B1
- Status: Granted
- Kind: B1
- Application number: 09/181,821
- Filed: 1998-10-29
- Granted: 2001-09-25
- Earliest claimed: 1997-10-29
- Assignees: Samsung Electronics Co., Ltd.
- Inventors: Won-il Jeong; Young-min Baik
- Web page: https://patentgrep.com/patent/US6294601B1

## CPC

- C03C 3/06: with more than 90% silica by weight, e.g. quartz {(C03C3/045 takes precedence)}
- C03C 1/006: {to produce glass through wet route}
- C03C 2203/22: using colloidal silica sols
- C03C 2203/30: Additives
- C03C 2203/34: adding silica powder
- C03C: CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS

## Abstract

A silica glass composition having silica and a binder is provided. The binder is methylcellulose or a polymer comprising repeating units represented by the formula (1): (—CH2—CH(OR)—) (1) where R is a C1-C12 alkyl group or is the acetyl group. The silica glass composition according to the present invention includes a binder cheaper than the conventional polyethyloxazoline and is not hazardous to humans. The air bubbles removing efficiency can be enhanced by reducing the viscosity of the sol, and the content of solid in the sol can be increased by using the silica glass composition according to the present invention. Also, the strength of the wet gel is increased allowing the gel to be easily handled in a subsequent process. The silica glass composition according to the present invention can be used in manufacturing silica glass for a semiconductor device and an optical lens as well as a tube for optical fiber.

## Claims

### Claim 1

A composition of matter for preparing silica glass, comprising:
silica and poly(vinyl acetate), the weight ratio of poly(vinyl acetate) to silica being in a range of from 0.05:100 to 1:100;
a quaternary ammonium hydroxide;
a polyhydric alcohol;
water-soluble aliphatic ester of an acid selected from the group consisting of lactic acid, formic acid and glycolic acid; and
a solvent.

### Claim 2 (depends on 1)

The composition of matter of claim 1, further comprised of the weight ratio of poly(vinyl acetate) to silica being in a range of from 0.1:100 to 0.6:100.
3.The composition of matter of claim 1, further comprised of the weight average molecular weight of said poly(vinyl acetate) being in a range of from 50,000 to 500,000.

### Claim 4

A composition of matter, for preparing silica glass, comprising:
silica and poly(vinyl acetate), the weight average molecular weight of the poly(vinyl acetate) being in a range of from 250,000 to 500,000;
a quaternary ammonium hydroxide;
a polyhydric alcohol;
water-soluble aliphatic ester of an acid selected from the group consisting of lactic acid, formic acid and glycolic acid; and
a solvent.