# US 6,294,570 B1 · Endosulfan microcapsule dispersion > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 6,294,570 B1 - Document ID: US6294570B1 - Status: Granted - Kind: B1 - Application number: 09/265,111 - Filed: 1999-03-09 - Granted: 2001-09-25 - Earliest claimed: 1999-03-09 - Assignees: Aventis CropScience GmbH - Inventors: Hans-Peter Krause; Thomas Maier; Jan Nicolaas Bremmer - Web page: https://patentgrep.com/patent/US6294570B1 ## CPC - A01N 25/28: Microcapsules {or nanocapsules} - A01N 43/24: with two or more hetero atoms - A01N: PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF (preservation of food or foodstuff A23); BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES (preparations for medical, dental or toiletry purposes which kill or prevent the growth or proliferation of unwanted organisms A61K); PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS ## Abstract Aqueous endosulfan microcapsule dispersions in which the dispersed microcapsules comprise endosulfan, an organic solvent or solvent mixture and a capsule-forming material based on isocyanate prepolymers and the aqueous phase which represents the dispersion medium comprises surfactants, a water-soluble inorganic salt with or without other formulation aids, which include a relatively small amount of capsule-forming material, and a process for their preparation. ## Claims ### Claim 1 An aqueous endosulfan microcapsule dispersion in which the dispersed microcapsules comprise endosulfan, an organic solvent or solvent mixture and a capsule-forming material based on isocyanate prepolymers and the aqueous phase, which represents the dispersion medium, comprises surfactants with or without other formulation aids, and which microcapsule dispersion, based on the total dispersion, comprises: 20-40% by weight of endosulfan; 10-35% by weight of organic solvent or solvent mixture; a capsule-forming material obtainable by curing 0.5-5% by weight of isocyanate prepolymers; 0.2-5% by weight of one or more surfactants selected from the group consisting of emulsifiers and dispersants and an amount of calcium chloride, wherein said amount is sufficient to produce a density of the aqueous phase of between 1.05 and 1.45 kg/l. ### Claim 2 (depends on 1) The microcapsule dispersion as claimed in claim 1, wherein the isocyanate prepolymer is an oil-soluble industrial mixed product of polyisocyanates based on condensates of aniline and formaldehyde. ### Claim 3 (depends on 1) The microcapsule dispersion as claimed in claim 1, wherein the capsule-forming material was obtained by curing the isocyanate prepolymers in the presence of water at 0-95° C. or with the required amount of a diamine. ### Claim 4 (depends on 1) The microcapsule dispersion as claimed in claim 1, wherein the capsule-forming material is obtainable by curing the isocyanate prepolymers with up to three times the stoichiometric amount of a diamine. ### Claim 5 (depends on 1) The microcapsule dispersion as claimed in claim 1, wherein the density of the aqueous phase is between 1.10 to 1.40 kg/l. ### Claim 6 (depends on 1) The microcapsule dispersion as claimed in claim 1, wherein the density of the aqueous phase is between 1.15 to 1.35 kg/l. ### Claim 7 (depends on 1) The microcapsule dispersion as claimed in claim 1 wherein the capsule-forming material is obtainable by curing the isocyanate prepolymers in the presence of water at 20-65° C. ### Claim 8 An aqueous endosulfan microcapsule dispersion in which the dispersed microcapsules comprise endosulfan, an organic solvent or solvent mixture and a capsule-forming material based on isocyanate prepolymers and the aqueous phase, which represents the dispersion medium, comprises surfactants with or without other formulation aids, and which microcapsule dispersion, based on the total dispersion, comprises: 20-35% by weight of endosulfan; 15-30% by weight of organic solvent or solvent mixture; capsule-forming material obtainable by curing 1-2% by weight of isocyanate prepolymers; 0.5-2% by weight of one or more surfactants selected from the group consisting of emulsifiers and dispersants; and an amount of calcium chloride, wherein said amount is sufficient to produce a density of the aqueous phase of between 1.05 and 1.45 kg/l. ### Claim 9 A process for preparing an aqueous endosulfin microcapsule dispersion in which the dispersed microcapsules comprise endosulfan, an organic solvent or solvent mixture and a capsule-forming material based on isocyanate prepolymers and the aqueous phase, which represents the dispersion medium, comprises surfactants with or without other formulation aids, and which microcapsule dispersion comprises, based on the total dispersion, 20-40% by weight of endosulfan; 10-35% by weight of organic solvent or solvent mixture; a capsule-forming material obtainable by curing 0.5-5% by weight of isocyanate prepolymers; 0.2-5% by weight of one or more surfactants selected from the group consisting of emulsifiers and dispersants; and an amount of calcium chloride, wherein said amount is sufficient to produce a density of the aqueous phase of between 1.05 and 1.45 kg/l, mwhich comprises preparing a coarse preemulsion of an organic and aqueous phase, then subjecting this to shear forces and, with or without addition of a diamine, curing the fine emulsion thus obtained in the entire volume of substance.