# US 6,294,080 B1 · Hydrocracking process product recovery method

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- Number: US 6,294,080 B1
- Document ID: US6294080B1
- Status: Granted
- Kind: B1
- Application number: 09/422,315
- Filed: 1999-10-21
- Granted: 2001-09-25
- Earliest claimed: 1999-10-21
- Assignees: Uop LLC
- Inventors: Vasant P. Thakkar; Christopher J. Anderle
- Web page: https://patentgrep.com/patent/US6294080B1

## CPC

- C10G 65/12: including cracking steps and other hydrotreatment steps
- C10G 49/22: Separation of effluents
- C10G 65/00: Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G: CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION (cracking to hydrogen or synthesis gas C01B; cracking or pyrolysis of hydrocarbon gases to individual hydrocarbons or mixtures thereof of definite or specified constitution C07C; cracking to cokes C10B); RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES

## Abstract

A feed stream is first processed in a hydrotreating reaction zone and then the effluent is separated into three fractions in an augmented first high pressure separator. Controlled portions of the middle and heavy boiling point range hydrocarbon fractions from this separator are recycled through a low conversion hydrocracking zone, while the remaining portions of these two fractions are passed into a second high pressure separator for recovery. The recycled hydrocarbons flow into a hydrocracking zone and the effluent of this zone flows into the hydrotreating reaction zone.

## Claims

### Claim 1

A method for recovering a product of a hydrocarbon conversion process which employs two reactors, which method comprises:
a) separating the effluent stream of a first reactor containing hydrotreating catalyst maintained at hydrotreating conditions in a first high pressure separator augmented with vessel internals to promote better separation and thereby producing a light process stream comprising hydrogen and normally vaporous hydrocarbons, an intermediate process stream, rich in hydrocarbons boiling between 300 and 700° F., and a heavy process stream rich in hydrocarbons having boiling points above 700° F.;
b) passing the light process stream, a first portion of the intennediate process stream and a first portion of the heavy process steam into a second high pressure separator operated at a pressure within about 100 psi of the first high pressure separator;
c) separating the chemical compounds entering the second high pressure separator into a vapor phase stream which is passed into a second reactor and a liquid phase stream which is passed into a product recovery zone, and recovering a distillate product stream from the product recovery zone.

### Claim 2 (depends on 1)

The process of claim 1 wherein a second portion equal to at least 25 vol percent of the intermediate process stream is passed directly into the second reactor.

### Claim 3 (depends on 2)

The process of claim 2 wherein a second portion equal to at least 25 vol. percent of the heavy process stream is passed into the second reactor.

### Claim 4 (depends on 3)

The process of claim 3 wherein the effluent of the second reactor is passed into the first reactor.

### Claim 5 (depends on 4)

The process of claim 4 wherein the second reactor contains hydrocracking catalyst maintained at hydrocracking conditions.

### Claim 6

A hydrocarbon conversion process which comprises:
a) passing a feed stream through a first reactor containing hydrotreating catalyst maintained at hydrotreating conditions, and producing a first effluent stream;
b) passing the first effluent stream into a first high pressure separator augmented with vessel internals to promote better separation and wherein the first effluent stream is separated into at least a light stream comprising hydrogen and normally vaporous hydrocarbons, an intermediate stream comprising hydrocarbons boiling between 300 and 700° F. and a heavy stream rich in hydrocarbons having boiling points above 700° F.;
c) passing the light stream, at least a first portion of the intermediate stream and at least a first portion of the heavy stream into a second high pressure separator operated at a pressure within about 100 psi of the first high pressure separator;
d) passing a second portion of the heavy stream through a second reactor which contains hydrocracking catalyst maintained at hydrocracking conditions and generating a second effluent stream;
e) passing the second effluent stream into the first reactor; and,
f) separating the chemical compounds entering the second high pressure separator into a vapor phase stream which is passed into the second reactor and a liquid phase stream which is passed into a product recovery zone, and recovering a distillate product stream from the product recovery zone.

### Claim 7 (depends on 6)

The process of claim 6 wherein a second portion of the intermediate stream is passed directly into the second reaction zone.

### Claim 8 (depends on 6)

The process of claim 6 wherein a second feed, having a lower average boiling point than the feed stream passed into the first reactor, is passed into the second reactor.

### Claim 9

A hydrocarbon conversion process which comprises:
a) passing a feed stream through a first reactor containing hydrotreating catalyst maintained at hydrotreating conditions, and producing a first effluent stream,
b) passing the first effluent stream into a first high pressure separator augmented with vessel internals to promote better separation and wherein the first effluent stream is separated into a light stream comprising hydrogen and normally vaporous hydrocarbons, an intermediate stream rich in hydrocarbons boiling between 300 and 700° F. and a heavy stream rich in hydrocarbons having boiling points above 700° F.;
c) passing the light stream, a first portion of the intermediate stream and a first portion of the heavy stream into a second high pressure separator operated at a pressure within 100 psi of the first high pressure separator;
d) passing a second portion of the heavy stream and a second portion of the intermediate stream through a second reactor which contains hydrocracking catalyst maintained at hydrocracking conditions and generating a second effluent stream;
e) passing the second effluent stream into the first reactor; and,
f) separating the chemical compounds entering the second high pressure separator into a vapor phase stream which is passed into the second reactor and a liquid phase stream which is passed into a product recovery zone; and,
g) recovering a distillate hydrocarbon product stream and an unconverted oil product stream from the product recovery zone.
