Method for producing shell catalysts for catalytic gas-phase oxidation of aromatic hydrocarbons
AssigneeBASF SE
InventorsThomas Heidemann, Thomas Cimniak, Bernhard Ulrich
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AssigneeBASF SE
InventorsThomas Heidemann, Thomas Cimniak, Bernhard Ulrich
Estimating the term…
The invention relates to a method for producing gas-phase catalysts gas-phase oxidation of aromatic hydrocarbons into carboxylic acids and/or carboxylic acid anhydrides upon whose carrier material a coating containing catalytically active metal oxide is applied in the form of a shell, wherein a powder is initially produced from a solution and/or suspension of catalytically active metal oxides and the precursor compounds thereof or simply the precursor compounds in the presence or absence of auxiliary agents in order to produce the catalyst. Said powder is then applied, in the form of a shell, to the carrier in the presence or absence of auxiliary agents after or without previous conditioning and without previous thermal treatment to produce the catalyst. The carrier which is thus coated undergoes thermal treatment in order to produce catalytically active metal oxides.
A process for producing coated catalysts for the catalytic gas-phase oxidation of aromatic hydrocarbons to give carboxylic acids and/or carboxylic anhydrides, on the support material of which a layer comprising catalytically active metal oxides is applied in the form of a shell, wherein a powder is first produced, by spray drying or freeze drying, from a solution and/or a suspension of the catalytically active metal oxides and their precursor compounds or these precursor compounds alone in the presence or absence of auxiliaries for catalyst production, the powder is subsequently applied as a paste in the form of a shell in the presence or absence of auxiliaries for catalyst production to the support after or without prior conditioning, without prior heat treatment to generate the catalytically active metal oxides and the support coated in this way is subjected to a heat treatment to generate the catalytically active metal oxides, the average layer thickness of the active composition of the coated catalysts produced in this way being from 10 to 250 μm.
Dependencies are inferred from the claim text.