# US 6,285,031 B1 · Radiation dosimetry method and associated apparatus > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 6,285,031 B1 - Document ID: US6285031B1 - Status: Granted - Kind: B1 - Application number: 09/216,349 - Filed: 1998-12-18 - Granted: 2001-09-04 - Earliest claimed: 1998-12-18 - Assignees: ISP Investments Inc. - Inventors: Carl A. Listl; David F. Lewis - Web page: https://patentgrep.com/patent/US6285031B1 ## CPC - G01T 1/06: Glass dosimeters {using colour change; including plastic dosimeters} - G01T: MEASUREMENT OF NUCLEAR OR X-RADIATION (radiation analysis of materials, mass spectrometry G01N23/00; tubes for determining the presence, intensity, density or energy of radiation or particles H01J47/00) ## Abstract A method and associated apparatus for monitoring exposure to radiation, with compensation for temperature variation of a sensor and variations in the amount of radiation sensitive material in a dosimeter used in the method. The method utilizes a radiation dosimeter having a layer of radiation sensitive material on a substrate, the radiation sensitive material having an optical absorbance which varies in accordance with degree of radiation exposure and wavelength and which also varies in dependence on temperature. The radiation sensitive layer includes a substantially radiation impervious substance. The method comprises exposing the layer of radiation sensitive material to a dose of radiation, optically measuring a spectral absorbance of the exposed layer of radiation sensitive material within a range of wavelengths, examining the measured spectral absorbance of the exposed layer of radiation sensitive material to determine an absorbance coordinate and a wavelength coordinate of a predetermined point on a spectral absorbance curve of the exposed layer of radiation sensitive material, and determining a radiation dose value associated with the absorbance coordinate and the wavelength coordinate. Generally, the radiation dose value is determined by consulting a table of absorbance and wavelength coordinates with associated dose values which have been previously measured for a batch of the radiation sensitive material, the batch having a uniform absorbance coefficient and a common concentration of the radiation sensitive material. The method can automatically compensate for variations in the amount of radiation sensitive material by adjusting the absorbance value of the radiation sensitive material by a measured value of absorbance in the radiation impervious substance. ## Claims ### Claim 1 A method for monitoring exposure to radiation, with compensation for temperature variation of a sensor, comprising: providing a radiation dosimeter including a layer of radiation sensitive material on a substrate, said radiation sensitive material having an optical absorbance which varies in accordance with degree of radiation exposure and wavelength and which also varies in dependence on temperature; exposing said layer of radiation sensitive material to a dose of radiation; after exposure of said layer of sensitive material to said dose of radiation, optically measuring a spectral absorbance of the exposed layer of radiation sensitive material within a range of wavelengths; examining the measured spectral absorbance of said exposed layer of radiation sensitive material to determine an absorbance coordinate and a wavelength coordinate of a predetermined point on a spectral absorbance curve of said exposed layer of radiation sensitive material; and determining a radiation dose value associated with said absorbance coordinate and said wavelength coordinate. ### Claim 2 (depends on 1) The method defined in claim 1 wherein the measuring of the spectral absorbance of the exposed layer of radiation sensitive material includes the step of operating a spectrophotometer. ### Claim 3 (depends on 2) The method defined in claim 2 wherein the examining of the measured spectral absorbance of said exposed layer of radiation sensitive material is implemented automatically. ### Claim 4 (depends on 3) The method defined in claim 3 wherein said predetermined point is a local maximum of said spectral absorbance curve and wherein the examining of the measured spectral absorbance of said exposed layer of radiation sensitive material includes automatically comparing absorbance values corresponding to successive wavelengths in a monotonic sequence with one another to detect a rising and a subsequent falling in the absorbance values, defining said local maximum. ### Claim 5 (depends on 2) The method defined in claim 2 wherein said layer of radiation sensitive material includes a substantially radiation impervious substance having a local maximum absorbance value, further comprising: operating said spectrophotometer to measure an absorbance of the radiation impervious substance in the exposed layer of radiation sensitive material; and adjusting the local maximum absorbance value in accordance with the measured value of the absorbance of the radiation impervious substance, to compensate for variation in a thickness of said layer of radiation sensitive material. ### Claim 6 (depends on 5) The method defined in claim 5 wherein the adjusting of the determined local maximum absorbance value includes multiplying the determined local maximum absorbance value by a ratio of a reference absorbance value and the measured value of the absorbance of the radiation impervious substance. ### Claim 7 (depends on 1) The method defined in claim 1 wherein the optical absorbance of said radiation sensitive material varies as a known function of radiation exposure and wavelength, said spectral absorbance curve being a contour or profile line of said function taken along a plane defined by said radiation dose. ### Claim 8 (depends on 1) The method defined in claim 1 wherein radiation of said dose of radiation has a wavelength shorter than wavelengths of the visible spectrum. ### Claim 9 (depends on 1) The method defined in claim 1 wherein the examining of the measured spectral absorbance of said exposed layer of radiation sensitive material is implemented automatically. ### Claim 10 (depends on 1) The method defined in claim 1 wherein said predetermined point is local maximum of said spectral absorbance curve and wherein the examining of the measured spectral absorbance of said exposed layer of radiation sensitive material includes comparing absorbance values corresponding to successive wavelengths with one another to detect a rising and falling in the absorbance values, corresponding to said local maximum. ### Claim 11 (depends on 1) The method defined in claim 1 wherein the examining of the measured spectral absorbance of said exposed layer of radiation sensitive material includes automatically comparing absorbance values corresponding to successive wavelengths with one another. ### Claim 12 (depends on 1) The method defined in claim 1 wherein said layer of radiation sensitive material includes a substantially radiation impervious substance having a determined local maximum absorbance value, further comprising: optically measuring an absorbance of the radiation impervious substance in the exposed layer of radiation sensitive material; and adjusting the determined local maximum absorbance value in accordance with the measured value of the absorbance of the radiation impervious substance, to compensate for thickness of said layer of radiation sensitive material. ### Claim 13 (depends on 12) The method defined in claim 12 wherein the adjusting of the determined local maximum absorbance value includes multiplying the local maximum absorbance value by a ratio of a reference absorbance value and the measured value of the absorbance of the radiation impervious substance. ### Claim 14 A method for monitoring exposure to radiation with compensation for variation in amount of detector material of a sensor, comprising: providing a radiation dosimeter including a layer of radiation sensitive material on a substrate, said radiation sensitive material having an optical absorbance which varies in dependence on thickness of said layer of radiation sensitive material, said layer of radiation sensitive material including a substantially radiation impervious substance having a determined local maximum absorbance value; exposing said layer of radiation sensitive material to a dose of radiation; after exposure of said layer of sensitive material to said dose of radiation, optically measuring an absorbance of the exposed layer of radiation sensitive material; measuring an absorbance of the radiation impervious substance in the exposed layer of radiation sensitive material; adjusting the determined absorbance of the radiation sensitive material in accordance with the measured value of the absorbance of the radiation impervious substance, to compensate for variation in a thickness of said layer of radiation sensitive material; and determining a radiation dose value from the adjusted absorbance value and its wavelength value. ### Claim 15 (depends on 14) The method defined in claim 14 wherein the adjusting of a determined local maximum absorbance value includes multiplying the determined local maximum absorbance value by a ratio of a reference absorbance value and the measured value of the absorbance of the radiation impervious substance. ### Claim 16 (depends on 14) The method defined in claim 14 wherein the measuring of the absorbance of the radiation impervious substance includes the step of operating a spectrophotometer. ### Claim 17 (depends on 14) The method defined in claim 14 wherein the optical absorbance of said radiation sensitive material varies as a known function of radiation exposure and wavelength, said spectral absorbance curve being a contour or profile line of said function taken along a plane defined by said radiation dose, wherein optically measuring an absorbance of the exposed layer of radiation sensitive material includes optically measuring a spectral absorbance of the exposed layer of radiation sensitive material within a range of wavelengths, and wherein the determining of said radiation dose value includes: examining the measured spectral absorbance of said exposed layer of radiation sensitive material to determine an absorbance coordinate and a wavelength coordinate of a predetermined point on a spectral absorbance curve of said exposed layer of radiation sensitive material; and determining a radiation dose value associated with said absorbance coordinate and said wavelength coordinate. ### Claim 18 An apparatus for determining exposure to radiation of an exposed radiation dosimeter including a layer of radiation sensitive material on a substrate, said radiation sensitive material having an optical absorbance which varies in accordance with degree of radiation exposure and wavelength and which also varies in dependence on temperature, comprising: optical sensing means for optically measuring a spectral absorbance of the exposed layer of radiation sensitive material within a range of wavelengths; spectral analysis means operatively connected to said optical sensing means for examining the measured spectral absorbance of said exposed layer of radiation sensitive material to determine an absorbance coordinate and a wavelength coordinate of a predetermined point on a spectral absorbance curve of said exposed layer of radiation sensitive material; and correlating means operatively connected to said spectral analysis means for determining a radiation dose value associated with said absorbance coordinate and said wavelength coordinate. ### Claim 19 (depends on 18) The apparatus defined in claim 18 wherein said optical sensing means includes a spectrophotometer. ### Claim 20 (depends on 19) The apparatus defined in claim 19 wherein said predetermined point is a local maximum of said spectral absorbance curve and wherein said spectral analysis means includes means for automatically comparing absorbance values corresponding to successive wavelengths in a monotonic sequence with one another to detect a rising and a subsequent falling in the absorbance values, defining said local maximum. ### Claim 21 (depends on 18) The apparatus defined in claim 18 wherein said layer of radiation sensitive material includes a substantially radiation impervious substance, and further comprising: means for measuring an absorbance of the radiation impervious substance in the exposed layer of radiation sensitive material; and thickness compensating means operatively connected to said correlating means for adjusting the determined absorbance value of a predetermined point in accordance with the measured value of the absorbance of the radiation impervious substance, to compensate for variation in a thickness of said layer of radiation sensitive material. ### Claim 22 (depends on 21) The apparatus defined in claim 21 wherein said thickness compensating means includes means for multiplying the determined absorbance value of a predetermined point by a ratio of a reference absorbance value and the measured value of the absorbance of the radiation impervious substance. ### Claim 23 (depends on 18) The apparatus defined in claim 18 wherein the optical absorbance of said radiation sensitive material varies as a known function of radiation exposure and wavelength, said spectral absorbance curve being a contour or profile line of said function taken along a plane defined by said radiation dose, radiation of said dose of radiation having a wavelength shorter than wavelengths of the visible spectrum. ### Claim 24 An apparatus for monitoring exposure to radiation of an exposed radiation dosimeter including a layer of radiation sensitive material on a substrate, with compensation for variation in thickness of said layer of radiation sensitive material, comprising: optical sensing means for optically measuring an absorbance of the radiation sensitive material in the exposed layer and for measuring an absorbance of the radiation impervious substance in the exposed layer; thickness compensating means operatively connected to said analysis means for adjusting the determined absorbance value of the radiation sensitive material and obtain a thickness corrected absorbance of the radiation sensitive material in accordance with the measured value of the absorbance of the radiation impervious substance, to compensate for variation in a thickness of said layer of radiation sensitive material; and analysis means operatively connected to said optical sensing means for determining a radiation dose value from the thickness corrected absorbance of the radiation sensitive material in said layer. ### Claim 25 (depends on 24) The apparatus defined in claim 24 wherein said thickness compensating means includes means for multiplying the determined absorbance value of the radiation sensitive material by a ratio of a reference absorbance value and the measured value of the absorbance of the radiation impervious substance. ### Claim 26 (depends on 24) The apparatus defined in claim 24 wherein said optical sensing means includes a spectrophotometer. ### Claim 27 (depends on 24) The apparatus defined in claim 24 wherein the optical absorbance of said radiation sensitive material varies as a known function of radiation exposure and wavelength, said spectral absorbance curve being a contour or profile line of said function taken along a plane defined by said radiation dose, wherein said optical sensing means includes means for optically measuring a spectral absorbance of the exposed layer of radiation sensitive material within a range of wavelengths, and wherein said analysis means includes: means for examining the measured spectral absorbance of said exposed layer of radiation sensitive material to determine an absorbance coordinate and a wavelength coordinate of a predetermined point on a spectral absorbance curve of said exposed layer of radiation sensitive material; and means for determining a radiation dose value associated with said absorbance coordinate and said wavelength coordinate.