Mesopore molecular sieve and process for the production thereof
AssigneesAsahi Kasei Kogyo Kabushiki Kaisha, The Noguchi Institute
InventorsMasahiko Koya, Hitoshi Nakajima, Itsuho Aishima
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AssigneesAsahi Kasei Kogyo Kabushiki Kaisha, The Noguchi Institute
InventorsMasahiko Koya, Hitoshi Nakajima, Itsuho Aishima
Estimating the term…
A mesopore molecular sieve having a hydrocarbon group bonded directly to a silicon atom in the metal oxide skeleton constituting the molecular sieve, wherein the content of said hydrocarbon group is from 0.01 to 0.6 mol per mol of the metal oxide. Also disclosed is a process for producing a mesopore molecular sieve having a hydrocarbon atom bonded to a silicon atom in the molecular sieve skeleton, which comprises synthesizing the mesopore molecular sieve, in the presence of a template, from: a silane compound represented by the following formula (1): RnSiX(4−n) (1) wherein R represents a hydrocarbon group selected from C1-16 hydrocarbon groups and hydrocarbon groups substituted with an N—, O-, S-, P- or halogen-containing group; n represents 1, 2 or 3; and X is selected from C1-6 alkoxy groups, aryloxy groups, a hydroxyl group and halogen atoms and a plurality of X may be the same or different; and a metal oxide and/or a precursor thereof. According to this process for producing a mesopore molecular sieve, a mesopore molecular sieve can be readily synthesized in one stage and, in addition, a mesopore molecular sieve having an excellent performance as an acid catalyst or oxidation catalyst can be obtained because the kind and amount of the hydrocarbon group can be easily adjusted.
A mesopore molecular sieve having an oxide skeleton and a hydrocarbon group bonded directly to a silicon atom on the oxide skeleton constituting the molecular sieve, wherein the content of said hydrocarbon group is from 0.01 to 0.6 mol per mol of the metal oxide.
A process for producing a mesopore molecular sieve having and a hydrocarbon group bonded to a silicon atom in the molecular sieve skeleton, which comprises synthesizing the mesopore molecular sieve, in the presence of a template, from:
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