# US 6,284,151 B1 · Chemical mechanical polishing slurry for tungsten

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- Number: US 6,284,151 B1
- Document ID: US6284151B1
- Status: Granted
- Kind: B1
- Application number: 08/997,289
- Filed: 1997-12-23
- Granted: 2001-09-04
- Earliest claimed: 1997-12-23
- Assignees: International Business Machines Corporation
- Inventors: Timothy C. Krywanczyk; Lawrence D. David
- Web page: https://patentgrep.com/patent/US6284151B1

## CPC

- C09K 3/1463: {Aqueous liquid suspensions}
- C09G 1/02: containing abrasives or grinding agents {(abrasives as such C09K3/14; polishing of semi-conductors H10P52/40)}
- H10P 52/403: {of conductive or resistive materials}
- C09K: MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09G: POLISHING COMPOSITIONS (French polish C09F11/00); SKI WAXES
- H10P: GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10

## Abstract

A ferric nitrate-alumina based slurry useful for Chemical-Mechanical-Polishing of tungsten metallurgy on semiconductor substrates in which the suspension and stability of abrasive material in the slurry is essentially stable. The slurry formulation is balanced to provide low residue of foreign material after polishing and due to its reduced ferric nitrate concentration will be less corrosive than prior art slurries. The recipe for the slurry includes 375 ml of a 9% wt alumina suspension, about 200 grams ferric nonahydrate, water to dilute to about 4.5 liters and enough 70% wt nitric acid to adjust the pH of the slurry to about 1.0 to 1.5.

## Claims

### Claim 1

The polishing slurry for CMP of metals consisting essentially of:
an aqueous solution containing a suspension of alumina;
an oxidizing agent comprising about 175 to 225 grams ferric nitrate hydrate;
water to provide about 4.5 liters of slurry; and
a quantity of 70% by weight nitric acid to provide a pH for the slurry of about 1.0 to 1.5.

### Claim 2 (depends on 1)

The polishing slurry of claim 1 wherein said aqueous solution of alumina comprises a dispersion of about 9% by weight alumina.

### Claim 3 (depends on 1)

The polishing slurry of claim 1 wherein there is provided about 200 grams of ferric nonahydride.

### Claim 4 (depends on 2)

The polishing slurry of claim 2 wherein said aqueous solution of alumina is about 375 ml.

### Claim 5

The polishing slurry for tungsten consisting essentially of:
about 375 ml stabilized alumina slurry have about 9% by weight alumina;
about 200 grams of ferric nonahydrate;
enough deionized water to dilute to about 4.5 liters; and
about 25 ml 70% by weight nitric acid.