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US 6,280,859 B1Granted
Light-emitting material for organo-electroluminescence device and for organic electroluminescence device which the material is applied
AssigneeToyo Ink Manufacturing Co., Ltd.
InventorsToshikazu Onikubo, Michiko Tamano, Satoshi Okutsu, Toshio Enokida
Life of this patent
Estimating the term…
Abstract
A light-emitting material which serves to emit light having a high brightness and is almost free of deterioration in light emission, and an organic EL device for which the light-emitting material is adapted, the material having the formula [1],
Claims6
A light-emitting material of the formula [1]
- wherein A is a substituted or non-substituted divalent aromatic group, a substituted or non-substituted hetero-aromatic divalent group, or a divalent group in which 2 to 10 identical or different groups out of the above groups are bonded to each other directly or through at least one of an oxygen atom, a nitrogen atom, a sulfur atom, a linear structural unit having 1 to 20 carbon atoms and optionally containing a hetero-atom, or a non-aromatic ring structural unit, with the proviso that A does not encompass a fused aromatic group or an amino group, each of Ar1 to Ar4 is independently a substituted or non-substituted aromatic group or a substituted or non-substituted fused aromatic group, each of X1 to X4 is independently >C═O, >SO2, —(CxH2x)—O—(CyH2y)— (in which each of x and y is an integer of 0 to 20, while x+y=0 in no case), a substituted or non-substituted alkylidene group having 2 to 20 carbons, a substituted or non-substituted alkylene group having 2 to 20 carbon atoms or a substituted or non-substituted divalent alicyclic residue, and each of R1 to R20 is independently a hydrogen atom, a halogen atom, a substituted or non-substituted alkyl group, a substituted or non-substituted alkoxy group, a substituted or non-substituted aromatic group, a substituted or non-substituted hetero-aromatic group or a substituted or non-substituted amino group (provided that adjacent groups of R1 to R5, R6 to R10, R11 to R15, or R16 to R20 may bond to each other to form a fresh ring).
A light-emitting material of the formula [4]
- wherein A is a substituted or non-substituted divalent aromatic group, a substituted or non-substituted hetero-aromatic divalent group, or a divalent group in which 2 to 10 identical or different groups out of the above groups are bonded to each other directly or through at least one of an oxygen atom, a nitrogen atom, a sulfur atom, a linear structural unit having 1 to 20 carbon atoms and optionally containing a hetero-atom, or a non-aromatic ring structural unit, with the proviso that A does not encompass a fused aromatic group or an amino group, each of X1 to X4 is independently >C═O, >SO2, —(CxH2x)—O—(CyH2x)— (in which each of x and y is an integer of 0 to 20, while x+y=0 in no case), a substituted or non-substituted alkylidene group having 2 to 20 carbons, a substituted or non-substituted alkylene group having 2 to 20 carbon atoms or a substituted or non-substituted divalent alicyclic residue, and each of R1 to R20 is independently a hydrogen atom, a halogen atom, a substituted or non-substituted alkyl group, a substituted or non-substituted alkoxy group, a substituted or non-substituted aromatic group, a substituted or non-substituted hetero-aromatic group or substituted or non-substituted amino group (provide that adjacent groups of R1 to R5, R6 to R10, R11 to R15, or R16 to R20 may bond to each other to form a fresh ring).
A light-emitting material of the formula [5]
- wherein A is a substituted or non-substituted divalent aromatic group, a substituted or non-substituted hetero-aromatic divalent group, or a divalent group in which 2 to 10 identical or different groups out of the above groups are bonded to each other directly or through at least one of an oxygen atom, a nitrogen atom, a sulfur atom, a linear structural unit having 1 to 20 carbon atoms and optionally containing a hetero-atom, or a non-aromatic ring structural unit, with the proviso that A does not encompass a fused aromatic group or an amino group, each of R1 to R20 is independently a hydrogen atom, a halogen atom, a substituted or non-substituted alkyl group, a substituted or non-substituted alkoxy group, a substituted or non-substituted aromatic group, a substituted or non-substituted hetero-aromatic group or a substituted or non-substituted amino group (provided that adjacent groups of R1 to R5, R6 to R10, R11 to R15, or R16 to R20 may bond to each other to form a fresh ring), and each of Y1 to Y8 is a substituted or non-substituted alkyl group having 1 to 20 carbon atoms or a substituted or non-substituted aromatic group having 6 to 16 carbon atoms (provided that groups of Y1 and Y2, Y3 and Y4, Y5 and Y6, or Y7 and Y8 may form a substituted or non-substituted alicyclic group having 5 to 7 carbon atoms).
Dependencies are inferred from the claim text.