Zeolite-containing oxidation catalyst and method of use
AssigneeEngelhard Corporation
InventorsBulent O. Yavuz, Kenneth E. Voss, Michel Deeba, John R. Adomaitis, Robert J. Farrauto
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AssigneeEngelhard Corporation
InventorsBulent O. Yavuz, Kenneth E. Voss, Michel Deeba, John R. Adomaitis, Robert J. Farrauto
Estimating the term…
Oxidation catalyst compositions for treating diesel exhaust include ceria and, optionally, alumina, each having a surface area of at least about 10 m2/g, and a zeolite, e.g., Beta zeolite. Optionally, platinum may be included in the catalytic material, preferably in amounts which are sufficient to promote some gas-phase oxidation of carbon monoxide (“CO”) and hydrocarbons (“HC”) but which are limited to preclude excessive oxidation of SO2 to SO3. Alternatively, palladium in any desired amount may be included in the catalytic material. The zeolite is optionally doped, e.g., ion-exchanged, with one or more of hydrogen, a platinum group metal or other catalytic metals. The catalyst compositions may be used in a method to treat diesel engine exhaust by contacting the hot exhaust with the catalyst composition to promote the oxidation of gas-phase CO and HC and of the volatile organic fraction component of particulates in the exhaust.
A method for treating a diesel engine exhaust stream comprising hydrocarbons selected from the group consisting of gaseous hydrocarbons and hydrocarbons present in a volatile organic fraction comprising the steps of:
A method for treating a diesel engine exhaust stream comprising hydrocarbons selected from the group consisting of gaseous hydrocarbons and hydrocarbons present in a volatile organic fraction comprising the step of contacting the stream with a catalyst composition consisting essentially of ceria having a BET surface area of at least about 10 m2/g, iron-doped Beta zeolite and, optionally, at least one catalytic metal selected from the group consisting of platinum and palladium.
Dependencies are inferred from the claim text.