Rare earth zirconium oxide buffer layers on metal substrates

Abstract

A laminate article comprises a substrate and a biaxially textured (RExA(1−x))2O2−(x/2) buffer layer over the substrate, wherein 0<x≦0.70 and RE is selected from the group consisting of La, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu. A is selected from the group consisting of Zr+4, Ce+4, Sn+4, and Hf+4. The (RExA(1−x))2O2−(x/2) buffer layer can be deposited using sol-gel or metal-organic decomposition. The laminate article can include a layer of YBCO over the (RExA(1−x))2O2−(x/2) buffer layer. A layer of CeO2 between the YBCO layer and the (RExA(1−x))2O2−(x/2) buffer layer can also be include. Further included can be a layer of YSZ between the CeO2 layer and the (RExA(1−x))2O2−(x/2) buffer layer. The substrate can be a biaxially textured metal, such as nickel. A method of forming the laminate article is also disclosed.

Dependencies are inferred from the claim text.