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US 6,269,858 B1Granted
Rubber containing starch reinforcement and tire having component thereof
AssigneeThe Goodyear Tire & Rubber Company
InventorPaul Harry Sandstrom
Life of this patent
Estimating the term…
Abstract
The present invention relates to a rubber composition containing a combination of starch, modified starch and/or starch/plasticizer composite together with selected methylene donor and/or methylene acceptor compounds. The invention also relates to tires having at least one component comprised of such rubber composition. Such tire component can be, for example, its circumferential tread or other component of the tire.
Claims16
A tire having at least one component of a rubber composition which comprises
- (A) 100 parts by weight of at least one diene-based elastomer,
- (B) about 2.5 to about 90 phr of at least one elastomer reinforcing filler composed of
- (1) about 5 to about 70 phr of at least one starch-based material selected from at least one of starch, starch/plasticizer composite and modified starch, wherein said modified starch is selected from at least one of hydroxyethylated starch, oxidized starch and acid modified starch, and
- 2) zero to about 90 phr of
- (a) carbon black and amorphous silica, or
- (b) carbon black or amorphous silica,
- (C) optionally a coupling agent for said starch-based material and silica, if silica is used, where said coupler has a moiety reactive with the surface of said starch composite and the surface of said silica, as the case may be, and a moiety interactive with the said elastomer, and
- (D) at least one methylene acceptor compound and/or methylene donor compound exclusive of hexamethylene tetramine;
- wherein said methylene acceptor compound is selected from at least one of phenolic cashew nut oil resin, resorcinol monobenzoate and polyhydric phenoxy resin;
- and
- wherein said methylene donor compound is selected from at least one of hexamethoxymethylmelamine, hexaethoxymethylmelamine and ethoxymethylpyridinium chloride, N,N′,N″-trimethylolmelamine, N-methylolmelamine and N′,N″-dimethylolmelamine.
8 more elements
Dependencies are inferred from the claim text.