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US 6,265,525 B1Granted
Method and device for manufacturing polycarbonate
AssigneeHitachi, Ltd.
InventorsTakatoshi Kinoshita, Kazunori Harada, Seiji Motohiro
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AssigneeHitachi, Ltd.
InventorsTakatoshi Kinoshita, Kazunori Harada, Seiji Motohiro
Estimating the term…
A process for producing polycarbonate designed to improve the quality of polycarbonate as a polymerization product polymer and reduce the investment and operating costs is provided. Polycarbonate is produced in two horizontal cylindrical agitation reactors provided with agitation blades successively extended through the vessel and partly with agitation blades having a screw function, as horizontally ganged together in series without any agitator center shaft, where the primary agitation reactor is a uniaxial horizontal agitation reactor with the agitation blades rotating at a low speed ranging from 1 rpm to 10 rpm, while keeping a clearance between the inner wall of the vessel ad the agitation blades in a range of 1 mm to 50 mm, and the secondary agitation reactor is a biaxial horizontal agitation reactor with agitation blades provided horizontally and in parallel, without any rotating center shaft, which conducts treatment by agitation at a low speed ranging from 1 rpm to 15 rpm.
A process for producing polycarbonate, which comprises a first step of subjecting a mixed liquid of diphenyl carbonate and an alcohol such as bisphenol A, etc. to agitating and mixing treatments in a uniaxial horizontal agitation reactor comprising a horizontal cylindrical vessel and agitation blades annularly distributed and successively arranged through the vessel and secured at positions deviated from the rotating axis toward the inner wall of the vessel without any agitator center shaft and a second step of subjecting the mixed liquid from the first step to agitation and mixing treatments in a horizontal biaxial agitation reactor with lattice blades, both steps being carried out at elevated temperatures ranging from 200° C. to 300° C. in vacuum less than or equal to the atmospheric pressure with increasing viscosity from 1 Pa·s to 5,000 Pa·s, thereby conducting polycondensation reaction of the mixed liquid and continuously producing polycarbonate.
An apparatus for producing polycarbonate, which comprises a uniaxial horizontal agitation reactor without any agitator center shaft comprising a horizontal cylindrical vessel and agitation blades annularly distributed and successively arranged through the vessel and secured at positions deviated from the rotating axis toward the inner wall of the vessel, to which diphenyl carbonate and an alcohol such as bisphenol A, etc. are fed as raw materials, followed by mixing and agitating treatments, and a horizontal biaxial agitation reactor with lattice blades for subjecting the mixed liquid from the uniaxial horizontal agitation reactor to agitating and mixing treatments, the agitating and mixing treatments in the two reactors being conducted at elevated temperatures ranging from 200° C. to 300° C. in vacuum less than or equal to the atmospheric pressure with increasing viscosity from 1 Pa·s to 5,000 Pa·s, thereby conducting polycondensation reaction of the mixed liquid and continuously producing polycarbonate.
A non-axial agitation apparatus, which comprises a horizontal cylindrical vessel, agitation blades annularly distributed and successively arranged through the vessel and secured at positions deviated from the rotating axis toward the inner wall of the vessel, screw members for pushing a liquid back inwardly being provided on the agitation blades positioned nearest to the side wall of the vessel.
Dependencies are inferred from the claim text.