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US 6,255,416 B1Granted
Method of producing conjugated diene polymers
AssigneeJsr Corporation
InventorsTakuo Sone, Katsutoshi Nonaka, Akio Takashima, Iwakazu Hattori
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Abstract
A conjugated diene polymer is obtained by using a specified catalyst system consisting of components (a)-(d) and indicating a high polymerization activity to a conjugated diene compound. Further, a modified conjugated diene polymer is obtained by reacting with at least one specified compound selected from the group consisting of components (e)-(j).
Claims8
A method of producing a conjugated diene polymer which comprises polymerizing at least one conjugated diene compound with a catalyst consisting essentially of the following components (a) to (d):
- Component (a):
- a compound containing a rare earth element of atomic number 57-71 in the Periodic Table or a compound obtained by reacting a compound containing a rare element of atomic number 57-71 with a Lewis base;
- Component (b):
- an aluminoxane;
- Component (c):
- an organoaluminum compound represented by general formula (1):
- AlR1R2R3 (1)
- wherein R1 and R2 are the same or different and are a hydrocarbon group having a carbon number of 1-10 or a hydrogen atom, and R3 is a hydrocarbon group having a carbon number of 1-10 provided that R3 is the same as or different from R1 or R2;
- and
- Component (d):
- a reaction product of a metal halide and a Lewis base.
8 more elements
Dependencies are inferred from the claim text.