Polyolefin microporous film and method for preparing the same
AssigneeTonen Chemical Corporation
InventorsKotaro Takita, Hidehiko Funaoka, Norimitsu Kaimai, Shigeaki Kobayashi, Koichi Kono
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AssigneeTonen Chemical Corporation
InventorsKotaro Takita, Hidehiko Funaoka, Norimitsu Kaimai, Shigeaki Kobayashi, Koichi Kono
Estimating the term…
It is an object of the present invention to provide a microporous polyolefin membrane, high in elongation and porosity, low in shrinkage, and capable of improving battery characteristics, safety and productivity, when used for battery separators. The microporous polyolefin membrane of the present invention comprises (A) an ultra-high-molecular-weight polyolefin having a weight-average molecular weight of 5×105 or more, or (B) a composition containing an ultra-high-molecular-weight polyolefin having a weight-average molecular weight of 5×105 or more, and having a porosity of 45 to 95%, elongation at break of 300% or more, bubble point exceeding 980 KPa and thermal shrinkage in the TD direction of 3% or less. The present invention also provides a method for producing the above microporous polyolefin membrane.
A method for producing the microporous polyolefin membrane having a weight-average molecular weight of 5×105 or more, and having a porosity 45 to 95%, tensile elongation of 300% or more, bubble point exceeding 980 Kpa and thermal shrinkage in the TD direction of 3% or less which comprises the steps of (a) preparing a solution comprising 10 to 50 wt. % of (A) an ultra-high-molecular-weight polyolefin having a weight-average molecular weight of 5×105 or more, or (B) a composition containing an ultra-high-molecular-weight polyolefin having a weight-average molecular weight of 5×105 or more, and 90 to 50 wt. % of a solvent, (b) extruding the solution, (c) quenching the extruded solution to have a gel-like extrudate, (d) biaxially stretching the gel-like extrudate at 116 to 125° C. at a stretching ratio of 2 or more in both MD and TD directions, (e) removing the solvent and drying the extrudate, and (f) heat-setting the extrudate at 115 to 120° C.
Dependencies are inferred from the claim text.