Phosphinic acid aluminum salts
AssigneeTicona LLC
InventorHans-Jerg Kleiner
Life of this patent
Estimating the term…
Abstract
Aluminum salts of phosphinic acid or diphosphinic acids having alkyl and/or aryl substitutes, obtainable by heating an ester of the corresponding phosphinic acids or diphosphinic acids with aluminum hydroxide at a temperature of more than 150° C. under pressure in the presence of water, are distinguished by a particular crystal structure and are suitable as flameproofing agents for plastics.
Claims6
A process for the preparation of high temperature modification aluminum salts of phosphinic acids or diphosphinic acids, which comprises reacting esters of the corresponding phosphinic acids or diphosphinic acids with aluminum hyroxide under pressure at 150 to 350° C. in the presence of water.
The process as claimed in claim 6, wherein said phosphoric esters or diphosphonic esters are the formula (III) or (IV)
- in which
- R1 and R2 are identical or different and are a C1-C8-alkyl or phenyl,
- R3 is a C1-C10-alkylene, an arylene, an alkylarylene, an arylalkylene, and
- R4 is a C1-C8-alkyl.
A process for the preparation of high temperature modification aluminum salts of phosphinic acids or diphosphinic acids, which comprises exposing an aluminum salt prepared by low temperature modification to temperatures in the range from 150 to 350° C., under pressure and in the presence of water and wherein said low temperature modification is at temperatures of 100° C. or less.
Dependencies are inferred from the claim text.