High strength plastic from reactive blending of starch and polylactic acids
AssigneeKansas State University Research Foundation
InventorsXiuzhi S. Sun, Paul Seib, Hua Wang
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Abstract
Biodegradable polymers for use in forming high strength, degradable plastics and methods of forming the polymers are provided. Broadly, the methods comprise forming and heating a blended mixture of polylactic acid, a starch, and a linkage group for joining or copolymerizing the polylactic acid and starch. Preferred linkage groups comprise an isocyanate moiety, with diphenylmethylene diisocyanate, hexamethylene diisocyanate, and isophorone diisocyanate. The reacted mixture can then be formed into the desired final product which has high tensile strength, modulus of elasticity, percent elongation, and thermal stability.
Claims49
A method of preparing a biodegradable polymer composition utilized in forming plastic articles, said method comprising the steps of:
- forming a mixture comprising starch, polylactic acid, and a linkage group comprising an isocyanate moiety;
- and
- causing said starch, polylactic acid, and linkage group to react to yield the polymer.
A biodegradable polymer composition utilized in forming plastics, said composition comprising a starch and polylactic acid reaction product, said composition having a tensile strength of at least about 50 MPa.
A biodegradable polymer composition utilized in forming plastics, said composition comprising a starch and polylactic acid reaction product, said polymer having a modulus of elasticity of at least about 1500 MPa.
A biodegradable polymer composition utilized in forming plastics, said composition comprising:
- a quantity of polylactic acid including a plurality of recurring monomers;
- a quantity of starch including a plurality of recurring monomers;
- and
- a linkage group bonded to at least one of said polylactic acid monomers and to at least one of said starch monomers.
Dependencies are inferred from the claim text.