Aluminum compounds and use thereof
AssigneeKao Corporation
InventorsMunehisa Okutsu, Tomohito Kitsuki, Katsumi Kita
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AssigneeKao Corporation
InventorsMunehisa Okutsu, Tomohito Kitsuki, Katsumi Kita
Estimating the term…
An aluminum compounds represented by the following general formula (1): Al(R1—SO3)1(R2)m(R3)n (1) wherein R1 is a hydrocarbon group which may be substituted, R2 is a hydrocarbon group which may be substituted, an aliphatic hydrocarbonoxy group which may be substituted, or a halogen atom, R3 is an aromatic hydrocarbonoxy group which may be substituted, and 1, m and n are independently a number of 0 to 3, with the proviso that 1+m+n equals 3, and 1 is not 0, an acid catalyst comprising the aluminum compound, and a process for producing an ester, acetal, ketal, ether or alkyl glycoside making use of the catalyst. The catalyst is suitable for use in a variety of acid-catalyzed reactions of alcohols, i.e., reactions with carbonyl compounds, such as esterification, transesterification, acetalization and ketalization, etherification, ring-opening reactions of epoxy compounds, etc. in addition to the above-described respective reactions, is not deactivated by alcoholysis, has a sufficient activity, can easily control a reaction catalyzed thereby and scarcely causes side reactions. Consequently, the use of the catalyst permits the production of the intended product at a high yield from starting materials used in an almost equimolar proportion.
An aluminum compound represented by the following general formula (1):
A process for producing an ester, acetal, ketal, ether or alkyl glycoside, which comprises reacting an alcohol with a carbonyl compound, alcohol, olefin, epoxy compound or sugar in the presence of an acid catalyst of an aluminum compound represented by the following general formula (1):
A process for producing an ester, acetal, ketal, ether or alkyl glycoside, which comprises reacting an alcohol with a carbonyl compound, alcohol, olefin, epoxy compound (except a vicinal alkylene oxide having 2 to 4 carbon atoms) or sugar in the presence of (A) an aluminum alkoxide and (B) a phenol and/or a sulfonic acid.
A process for producing an ether, which comprises reacting an alcohol with an epoxy compound in the presence of (A) an aluminum alkoxide and (B) a phenol and/or a sulfonic acid.
Dependencies are inferred from the claim text.