Hydrolyzable silane emulsions and method for preparing the same
AssigneeCrompton Corporation
InventorsToshiko M. Maeda, Antonio Chaves
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Abstract
The present invention relates to a process of preparing emulsions of hydrolyzable silanes, such as alkoxysilanes, using an oil concentrate. The emulsifiers are initially stirred with water. An oil concentrate is then prepared by adding a hydrolyzable silane to the stirring mixture of emulsifiers and water. Additional water is then dispersed in the oil concentrate to form the desired emulsion. Emulsions prepared by this process have shelf stability that is 6 months or longer.
Claims20
A process for preparing an oil-in-water emulsion comprising at least one hydrolyzable silane, at least one emulsifier, and water, comprising the steps of:
- I) dispersing at least one emulsifier in water at a weight ratio of 1.5:1.0 to about 1.0:4.0;
- II) preparing an oil concentrate by mixing said emulsifier and water blend with at least one hydrolyzable silane having the general formula:
- R1aR2bSi(OR3)[4−a−b]4−a−b
- wherein
- R1 is a hetero atom substituted hydrocarbon group;
- R2 is independently an unsubstituted hydrocarbon group;
- R3 is an alkyl, alkoxyalkyl, aryl or aralkyl radical having from 2 to 10 carbon atoms;
- and
- a is 0 to 3, b is 0 to 2;
- with the proviso that a+b=1,2 or 3;
- and each R group is cyclic, branched or linear;
- and
- such that said oil concentrate comprises about 1 part to about 28 parts of said emulsifier and about 1 part to about 55 parts water, per 100 parts of said at least one hydrolyzable silane and
- III) slowly adding water to said oil concentrate until inversion of said oil concentrate occurs.
Dependencies are inferred from the claim text.