Fibers and fibrous moldings made by using the same
AssigneeChisso Corporation
InventorsYuji Nakajima, Morio Abe
Life of this patent
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Abstract
The present invention provides a fiber containing remarkably high heat resistance and softness and fiber-processed products using the same. A fiber formed from a polypropylene serving as at least one raw material, wherein the polypropylene is confirmed with NMR spectrometry that an isotactic pentad fraction (mmmm) of 0.950-0.995, a syndiotactic pentad fraction (rrrr) of 0-0.004, different bonds due to 2,1-insertion reaction and 1,3-insertion reaction in an amount of 0-0.3 mol %, and absence of terminal double bonds, and has a weight average molecular weight (Mw) of 50,000-1,000,000, and has a ratio (Mw/Mn) of weight average molecular weight (Mw) to number average molecular weight (Mn) of 1.5-3.8; and fiber-processed products using the fiber.
Claims20
A fiber formed from a polypropylene serving as at least one raw material, wherein the polypropylene has
- (a) an isotactic pentad fraction (mmmm) of 0.950-0.995,
- (b) a syndiotactic pentad fraction (rrrr) of 0-0.004,
- (c) different bonds due to 2,1-insertion reaction and 1,3-insertion reaction in an amount of 0-0.3 mol %, and
- (d) absence of terminal double bonds, each of which was confirmed with NMR spectrometry, and has
- (e) a weight average molecular weight (Mw) of 50,000-1,000,000 and
- (f) a ratio (Mw/Mn) of weight average molecular weight (Mw) to number average molecular weight of 1.5 to 3.8,
- said polypropylene being manufactured through the use of a chiral transition metal compound represented by the following formula
- wherein each of C5H4−m and C5H4−nR2n represents a substituted cyclopentadienyl group;
- each of m and n represents an integer of 1-3;
- each of R1 and R2, which may be identical to or different from each other, represents a C1-20 hydrocarbon group;
- a silicon-containing hydrocarbon group, or a hydrocarbon group bonding to two carbon atoms contained in the cyclopentadienyl ring thereby to form one or more hydrocarbon rings which may have ring hydrogen further substituted with a hydrocarbon group;
- Q represents a group that can be cross-linked with C5H4−m, R1m and C5H4−nR2n, non-substituted silylene, or hydrocarbon-substituted silylene group;
- M represents a transition metal selected from a group of titanium, zirconium, and hafnium;
- and each of X and Y, which may be identical to or different from each other, represents hydrogen, a halogen, or a hydrocarbon group, as catalyst in the presence of hydrogen.
Dependencies are inferred from the claim text.