Liquid crystal composition and liquid crystal display element
AssigneeChisso Corporation
InventorsToshihiko Muraoka, Katsuyuki Murashiro, Fusayuki Takeshita, Tetsuya Matsushita, Etsuo Nakagawa
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Abstract
A liquid crystal composition which has a superior voltage transmittance (sharpness) for good color and high-speed response characteristics. The composition contains at least one of the following first component (I-a, I-b), second component (II-a to II-d) and third component (III-a to III-c) respectively: wherein R1, R2, Z0, Z1, Q1, A1, A3, p, q, m and n are defined in the specification.
Claims12
A liquid crystal composition comprising a first component which is at least one member selected from the group consisting of compounds expressed by the formulae (I-a) and (1-b)
- wherein R1 denotes an alkyl group having from 1 to 10 carbon atoms wherein one CH2 group may be replaced by oxygen atom or —CH═CH— group;
- and n denotes 0 to 20,
- a second component which is at least one member selected from the group consisting of compounds expressed by the formulae II-a, II-b, II-c and II-d
- wherein R1 denotes an alkyl group having from 1 to 10 carbon atoms wherein one CH2 group may be replaced by oxygen atom or —CH═CH— group;
- and n denotes 0 to 20, and
- a third component which is at least one member selected from the group consisting of compounds expressed by the formulae III-a, III-b and III-c
- wherein R2 denotes an alkyl group having from 1 to 10 carbon atoms wherein one CH2 group may be replaced by oxygen atom or —CH═CH— group;
- Z0 denotes —COO— or —CH2CH2—;
- Z1 denotes —CH2CH2—, —COO— or a single bond;
- Q1 denotes H or F;
- A1 denotes trans-1,4-cyclohexylene, 1,4-phenylene or 1,3-dioxane-2,5-diyl;
- A2 and A3 each independently denote trans-1,4-cyclohexylene or 1,4-phenylene;
- and p, q and m each independently denote 0 or 1.
A liquid crystal composition comprising a first component which is at least one member selected from the group consisting of compounds expressed by the formulae (I-a) and (I-b)
- wherein R1 denotes an alkyl group having from 1 to 10 carbon atoms wherein one CH2 group may be replaced by oxygen atom or —CH═CH— group;
- and n denotes 0 to 20,
- a second component which is at least one member selected from the group consisting of compounds expressed by the formulae II-a, II-b, II-c and II-d
- wherein R1 denotes an alkyl group having from 1 to 10 carbon atoms wherein one CH2 group may be replaced by oxygen atom or —CH═CH— group;
- and n denotes 0 to 20,
- a third component which is at least one member selected from the group consisting of compounds expressed by the formulae III-a, III-b and III-c
- wherein R2 denotes an alkyl group having from 1 to 10 carbon atoms wherein one CH2 group may be replaced by oxygen atom or —CH═CH— group;
- Z0 denotes —COO— or —CH2CH2—;
- Z1 denotes —CH2CH2—, —COO— or a single bond;
- Q1 denotes H or F;
- A1 denotes trans-1,4-cyclohexylene, 1,4-phenylene or 1,3-dioxane-2,5-diyl;
- A2 and A3 each independently denote trans-1,4-cyclohexylene or 1,4-phenylene;
- and p, q and m each independently denote 0 or 1, and
- a fourth component which is at least one member selected from the group consisting of compounds expressed by the formulae IV, V, VI-a and VI-b
- R3-(B)-Z2-(C)-R4 (IV)
- wherein R1 and R4 each independently denote an alkyl group having from 1 to 10 carbon atoms wherein one CH2 group may be replaced by oxygen atom or —CH═CH— group;
- B denotes trans-1,4-cyclohexylene, pyrimidine-2,5-diyl or 1,4-phenylene;
- C denotes trans-1,4-cyclohexylene or 1,4-phenylene;
- and Z2 denotes —C≡C—, —COO—, —CH2CH2—, —CH═CH—, —CF═CF— or a single bond,
- R5-(D)-Z3-(E)-Z4-(G)-R6 (V)
- wherein R5 denotes an alkyl group having from 1 to 10 carbon atoms wherein one CH2 group may be replaced by oxygen atom or —CH═CH— group;
- R6 denotes an alkyl group, an alkoxy group or an alkoxymethyl group having from 1 to 10 carbon atoms;
- D denotes trans-1,4-cyclohexylene or pyrimidine-2,5-diyl;
- E denotes trans-1,4-cyclohexylene or 1,4-phenylene in which one H at a 2-, 3-, 5- or 6-position may be optionally replaced by F;
- G denotes trans-1,4-cyclohexylene or 1,4-phenylene;
- Z3 denotes —CH2CH2 or a single bond;
- and Z4 denotes —C≡C—, —COO—, —CH═CH— or a single bond,
- wherein R7 denotes an alkyl group having from 1 to 10 carbon atoms wherein one CH2 group may be replaced by oxygen atom or —CH═CH— group;
- R8 denotes an alkyl group, an alkoxy group or an alkoxymethyl group having from 1 to 10 carbon atoms;
- and Q2 denotes H or F.
A liquid crystal composition comprising a first component which is at least one member selected from the group consisting of compounds expressed by the formulae (I-a) and (I-b)
- wherein R1 denotes an alkyl group having from 1 to 10 carbon atoms wherein one CH2 group may be replaced by oxygen atom or —CH═CH— group;
- and n denotes 0 to 20,
- a second component which is at least one member selected from the group consisting of compounds expressed by the formulae II-a, II-b, II-c and II-d
- wherein R1 denotes an alkyl group having from 1 to 10 carbon atoms wherein one CH2 group may be replaced by oxygen atom or —CH═CH— group;
- and n denotes 0 to 20,
- a third component which is at least one member selected from the group consisting of compounds expressed by the formulae III-a, III-B and III-c
- wherein R2 denotes an alkyl group having from 1 to 10 carbon atoms wherein one CH2 group may be replaced by oxygen atom or —CH═CH— group;
- Z0 denotes —COO— or —CH2CH2—;
- Z1 denotes —CH2CH2—, —COO— or a single bond;
- Q1 denotes H or F;
- A1 denotes trans-1,4-cyclohexylene, 1,4-phenylene or 1,3-dioxane-2,5-diyl;
- A2 and A3 each independently denote trans-1,4-cyclohexylene or 1,4-phenylene;
- and p, q and m each independently denote 0 or 1,
- a fourth component which is at least one member selected from the group consisting of compounds expressed by the formulae IV, V, VI-a and VI-b
- R3-(B)-Z2-(C)-R4 (IV)
- wherein R3 and R4 each independently denote an alkyl group having from 1 to 10 carbon atoms wherein one CH2 group may be replaced by oxygen atom or —CH═CH— group;
- B denotes trans-1,4-cyclohexylene, pyrimidine-2,5-diyl or 1,4-phenylene;
- C denotes trans-1,4-cyclohexylene or 1,4-phenylene;
- and Z2 denotes —C≡C—, —COO—, —CH2CH2—, —CH═CH—, —CF═CF— or a single bond,
- R5-(D)-Z3-(E)-Z4-(G)-R6 (V)
- wherein R5 denotes an alkyl group having from 1 to 10 carbon atoms wherein one CH2 group may be replaced by oxygen atom or —CH═CH— group;
- R6 denotes an alkyl group, an alkoxy group or an alkoxymethyl group having from 1 to 10 carbon atoms;
- D denotes trans-1,4-cyclohexylene or pyrimidine-2,5-diyl;
- E denotes trans-1,4-cyclohexylene or 1,4-phenylene in which one H at a 2-, 3-, 5- or 6-position may be optionally replaced by F;
- G denotes trans-1,4-cyclohexylene or 1,4-phenylene;
- Z3 denotes —CH2CH2— or a single bond;
- and Z4 denotes —C≡C—, —COO—, —CH═CH— or a single bond,
- wherein R7 denotes an alkyl group having from 1 to 10 carbon atoms wherein one CH2 group may be replaced by oxygen atom or —CH═CH— group;
- R8 denotes an alkyl group, an alkoxy group or an alkoxymethyl group having from 1 to 10 carbon atoms;
- and Q2 denotes H or F, and
- a fifth component which is at least one member selected from the group consisting of compounds expressed by the formulae VII and VIII
- wherein R9 denotes an alkyl group having from 1 to 10 carbon atoms;
- Q3 denotes H or F:
- and k denotes 0 or 1,
- wherein R10 denotes an alkyl group having from 1 to 10 carbon atoms;
- J denotes trans-1,4-cyclohexylene or 1,4-phenylene;
- Q4 and Q5 each independently denote H or F;
- Z5 and Z6 each independently denote —COO— or a single bond;
- and h denotes 0, 1 or 2.
Dependencies are inferred from the claim text.