Catalytic converter with metal monolith having an integral catalyst
AssigneeAlliedSignal Inc.
InventorsGeorge Ronald Lester, Stephen Thomas Homeyer
Life of this patent
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Abstract
An improved catalytic converter which comprises a metal monolith made of aluminum or aluminum alloy having an anodized surface layer on which is disposed catalytic metals, particularly noble metals from Group VIII and optionally base metals. In a preferred embodiment the metal monolith employs plate fin elements defining a large plurality of fins arranged in an axial succession of offset fin rows. The catalytic converter has application in the conversion of ozone and the oxidation of atmospheric pollutants.
Claims20
A monolithic catalytic converter comprising
- (a) a unitary aluminum or aluminum alloy support within a housing providing tortuous flow paths for gases passing over said support and having an integral anodized surface layer at least 2 μm thick, said support comprising one or more plate fin elements having a plurality of fins arranged in an axial succession of offset fin rows, said anodized surface layer being formed by anodizing at a temperature of about 30°-37° C., followed by washing and optionally calcining said anodized surface layer at a temperature of 150° to 540° C.;
- and
- (b) one or more Group VIII noble metals and optionally base metals from Groups VIII, IIIa, and VIIa disposed on and within said anodized surface layer of (a).
A method of destroying ozone in air comprising passing ozone-containing air through a monolithic catalytic converter comprising
- (a) a unitary aluminum or aluminum alloy support within a housing providing tortuous flow paths for gases passing over said support and having an integral anodized surface layer at least 2 μm thick, said support comprising one or more plate fin elements having a plurality of fins arranged in an axial succession of offset fin rows, said anodized surface layer being formed by anodizing at a temperature of about 30°-37° C., followed by washing and optionally calcining at a temperature of 150° to 540° C.;
- and
- (b) one or more Group VIII noble metals and optionally base metals from Groups VIII, IIIa, and VIIa disposed on and within said anodized surface layer of (a).
A method of destroying atmospheric pollutants by oxidation comprising passing air containing pollutants through a monolithic catalytic converter comprising
- (a) a unitary aluminum or aluminum alloy support within a housing providing tortuous flow paths for gases passing over said support and having an integral anodized surface layer at least 2 μm thick, said support comprising one or more plate fin elements having a plurality of fins arranged in an axial succession of offset fin rows, said anodized surface layer being formed by anodizing at a temperature of about 30°-37° C., followed by washing and optionally calcining at a temperature of about 150° to 540° C.;
- and
- (b) one or more Group VIII noble metals and optionally base metals from Groups Ib, IIb, IIIa, IVa, Va, VIa, VIIa, and VIII disposed on and within said anodized surface layer of (a).
A monolithic catalytic converter comprising
- (a) a unitary aluminum or aluminum alloy support within a housing providing tortuous flow paths for gases passing over said support and having an integral anodized surface layer at least 2 μm thick, said support comprising one or more plate fin elements having a plurality of fins arranged in an axial succession of offset fin rows, said anodized surface layer being formed by passing a direct current of about 9 amps/ft2 and about 8 to 15 volts through said aluminum or aluminum alloy support as an anode in an electrolytic bath comprising 5-20 wt. % aqueous sulfuric acid at a constant temperature of about 30° to 37° C., and thereafter washing said anodize surface layer with water and optionally calcining at a temperature in the range of 150° to 540° C.;
- and
- (b) one or more Group VIII noble metals and optionally base metals from Groups VIII, IIIa, and VIIa disposed on and within said anodized and calcined surface layer of (a).
A method of preparing an integral anodized catalytic surface layer on the surface of an aluminum or aluminum alloy consisting essentially of
- (a) anodizing said surface by passing a direct current of about 9 amps/ft2 and about 8 to 15 volts through said aluminum or aluminum alloy surface in an electrolytic bath comprising 5-20 wt. % aqueous sulfuric acid at a constant temperature of 30° to 37° C.;
- (b) washing said anodized surface of (a) and optionally calcining said washed surface at a temperature in the range of 150° to 540° C.;
- (c) impregnating said washed and optionally calcined surface of (b) with solutions of compounds of one or more Group VIII noble metals and optionally with base metals from Groups Ib, IIb, IIIa, IVa, Va, VIa, VIIa, and VIII;
- and
- d) heating said impregnated surface of (c) to decompose said metal compounds.
Dependencies are inferred from the claim text.