US 6,203,720 B1Granted

Low MFT and high Tg , internally plasticizing, and low voc latex compositions

AssigneeThe University of Southern Mississippi

InventorsShelby Freland Thames, Kamlesh Gopichand Panjnani, Rajan Hariharan, Zhiyu Wang

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Abstract

Novel latex or emulsion compositions containing internally plasticizing and crosslinkable monomers derived from traditional semi-drying or non-drying oils are disclosed and claimed. The monomers are ethylenically unsaturated esters of long-chain olefinic compounds. Preferred embodiments include latex formed from acrylate or methacrylate esters of hydroxy fatty acid esters derived from castor oil or lesquerella oil. A process for the synthesis of the latex composition is also disclosed, which involves (a) an esterification reaction of ethylenically unsaturated carboxylic acid or its derivatives with a substituted hydroxy long-chain olefinic compound; (b) subsequent polymerization of the so formed ethylenically unsaturated ester of a long-chain olefinic compound in an aqueous phase with at least one other copolymerizable monomer; and (c) blending so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions. These compositions form films at low minimum film forming temperatures (MFT) ranging from −5 to 10° C. and cure to above ambient glass transition (Tg) polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These compositions are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.

Claims8

Dependent claims

A composition suitable for forming latex or emulsion formulations comprising an aqueous dispersion composed of a blended mixture of:

(a) a derivative of a non-drying oil having an ethylenically unsaturated carboxylic acid ester of the formula:
(b) at least one copolymerizable monomer selected from the group consisting of vinyl acetate, vinyl chloride, vinyl ester of C5-C12 saturated tertiary branched carboxylic acids, acrylonitrile, acrylamide, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, glycidyl acrylate, glycidyl methacrylate, acrylic acid, butyl acrylate, butyl methacrylate, methyl methacrylate, methyl acrylate, para-acetoxystyrene, and styrene;
(c) a drier selected from the group consisting of aliphatic carboxylic acid salts of cobalt, manganese, lead, zirconium, calcium, and mixtures thereof;
and
(d) one or more of anionic, cationic, amphoteric, or nonionic surface-active agent;
wherein (i) R is either methyl or a multifunctional moiety having the structure:
where R12 and R13 are the same or different and are independently selected from the group consisting of a saturated or unsaturated fatty acid chain;
(ii) R9 is either hydrogen or methyl;
(iii) a, a′, b, b′, and c, are integers, where a and a′ have a value of from 2 to 4, b and b′ have a value of 0 to 2 with the proviso that the sum of b and b′ is 1 or 2, and c has a value of 5 to 12;
and
(iv) the total weight percent of (a) and (b) in said aqueous dispersion is at least from about 5 and not more than about 60 weight percent, based on total weight of the composition, wherein (a) and (b) are present in the weight ratio ranging from about 1:7 to about 1:20.

8 more elements

Dependencies are inferred from the claim text.