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US 6,203,154 B1Granted
Electrochromic element
AssigneeNippon Mitsubishi Oil Corporation
InventorsMasaaki Kobayashi, Izuru Sugiura, Yoshinori Nishikitani
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Abstract
An electrochromic element composed of an electrochromic layer comprising a specified electrically conductive polymer and an ionically conductive substance layer containing a viologen compound, both sandwiched between two electrically conductive substrates at least one of which is transparent.
Claims6
An electrochromic element comprising two conductive substrates, at least one of which is transparent;
- an ion conductive layer disposed therebetween and containing a compound having a viologen structure represented by formula (1) below;
- and an electrochromic layer disposed between the ion conductive layer and at least either one of the two conductive substrates and containing a compound represented by formula (2) or (3) below;
- formula (1) being represented by
- wherein X− and Y− may be the same or different and each are a counter anion selected from the group consisting of a halogen anion, ClO4−, BF4−, PF6−, CH3COO− and CH3(C6H4)SO3−;
- formula (2) being represented by
- wherein R1 is hydrogen or an alkyl group having 1 to 5 carbon atoms, R2, R3, R4 and R5 are each independently a hydrocarbon group or hydrocarbon residue having 1 to 20 carbon atoms and may be the same or different from each other, Ar1 and Ar2 are each independently a divalent aromatic hydrocarbon residue having 6 to 20 carbon atoms, a is an integer greater than 2 and b and c are each an integer of 0 to 3;
- and
- formula (3) being represented by
- wherein R6, R7, R8, R9 and R10 are each independently hydrogen or a hydrocarbon group residue having 1 to 20 carbon atoms, Ar4 and Ar5 are each independently a divalent aromatic hydrocarbon residue, a′ is an integer of 0 to 3, b′ is an integer of 1 or 2 and c′ is an integer greater than 2.
6 more elements
Dependencies are inferred from the claim text.