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AssigneeUnion Carbide Chemicals & Plastics Technology Corporation
InventorsAnil Sakharam Guram, John Robert Briggs, Kurt Damar Olson, Thomas Carl Eisenschmid, Diane Lee Packett, Erik Bruce Tjaden
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This invention relates in part to processes for producing one or more substituted or unsubstituted unsaturated alcohols which comprise reacting one or more substituted or unsubstituted alkadienes with carbon monoxide and hydrogen in the presence of a metal-ligand complex catalyst and a promoter and optionally free ligand to produce said one or more substituted or unsubstituted unsaturated alcohols. The substituted and unsubstituted unsaturated alcohols produced by the processes of this invention can undergo further reaction(s) to afford desired derivatives thereof. This invention also relates in part to reaction mixtures containing one or more substituted or unsubstituted unsaturated alcohols as principal product(s) of reaction.
A process for producing one or more substituted or unsubstituted unsaturated alcohols which comprises reacting one or more substituted or unsubstituted alkadienes with carbon monoxide and hydrogen in the presence of a metal-ligand complex catalyst and a promoter and optionally free ligand to produce said one or more substituted or unsubstituted unsaturated alcohols, wherein said promoter comprises an organic or inorganic compound with an ionizable hydrogen of pKa of from about 1 to about 35.
A process for producing one or more substituted or unsubstituted unsaturated alcohols which comprises reacting one or more substituted or unsubstituted alkadienes with carbon monoxide and hydrogen in the presence of a metal-organophosphorus ligand complex catalyst and a promoter and optionally free organophosphorus ligand to produce said one or more substituted or unsubstituted unsaturated alcohols wherein said promoter comprises an organic or inorganic compound with an ionizable hvdrogen of pKa of from about 1 to about 35.
A process for producing one or more substituted or unsubstituted penten-1-ols which comprises reacting one or more substituted or unsubstituted butadienes with carbon monoxide and hydrogen in the presence of a metal-organophosphorus ligand complex catalyst and a promoter and optionally free organophosphorus ligand to produce said one or more substituted or unsubstituted penten-1-ols wherein said promoter comprises an organic or inorganic compound with an ionizable hydrogen of pKa of from about 1 to about 35.
A process for producing a batchwise or continuously generated reaction mixture comprising:
A process for producing a reaction mixture comprising one or more substituted or unsubstituted unsaturated alcohols which process comprises reacting one or more substituted or unsubstituted alkadienes with carbon monoxide and hydrogen in the presence of a metal-ligand complex catalyst and a promoter and optionally free ligand to produce said reaction mixture comprising one or more substituted or unsubstituted unsaturated alcohols, wherein said promoter comprises an organic or inorganic compound with an ionizable hydrogen of pKa of from about 1 to about 35.
A process for producing a reaction mixture comprising one or more substituted or unsubstituted penten-1-ols which process comprises reacting one or more substituted or unsubstituted butadienes with carbon monoxide and hydrogen in the presence of a metal-organophosphorus ligand complex catalyst and a promoter and optionally free organophosphorus ligand to produce said reaction mixture comprising one or more substituted or unsubstituted penten-1-ols, wherein said promoter comprises an organic or inorganic compound with an ionizable hydrogen of pKa of from about 1 to about 35.
Dependencies are inferred from the claim text.