Weatherable resinous composition having improved opacity and impact strength
AssigneeBayer Aktiengesellschaft
InventorsMoh Ching Oliver Chang, Richard M. Auclair, Robert A. Sanocki
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AssigneeBayer Aktiengesellschaft
InventorsMoh Ching Oliver Chang, Richard M. Auclair, Robert A. Sanocki
Estimating the term…
A thermoplastic molding composition comprising a grafted rubber and a copolymeric matrix is disclosed. The composition is characterized in that its grafted rubber includes a substrate, a first grafted phase and a subsequent grafted phase which are sequentially grafted to said substrate. The substrate which contains a crosslinked elastomer is grafted with a first grafted phase and with a subsequent grafted phase, both phases containing copolymers of at least one vinylaromatic monomer and at least one member selected from the group consisting of (meth)acrylonitrile and alkyl (meth)acrylate. The relative ratios of the monomers making up the copolymerized phases differ one from the other. The grafted rubber is present in particulate form having a weight average particle size of about 0.1 to 1.0 microns. The composition features improved impact strength and reduced opacity.
A thermoplastic molding composition comprising a grafted rubber and a copolymeric matrix wherein grafted rubber includes a substrate, a first grafted phase and a subsequent grafted phase which are sequentially grafted to said substrate, wherein substrate contains a crosslinked elastomer selected from the group consisting of polyalkyl acrylate and hydrogenated polydiene, and said first grafted phase contains a copolymer consisting of at least one vinylaromatic monomer and at least one member selected from the group consisting of (meth)acrylonitrile and alkyl (meth)acrylate, said vinylaromatic monomer and said member relating by weight as 90/10 to 80/20 and where said subsequent grafted phase contains a copolymer of about 70 to 75 percent relative to the weight of said subsequent grafted phase of at least one vinylaromatic monomer, and about 25 to 30 percent relative to the weight of said subsequent grafted phase of at least one member selected from a second group consisting of (meth)acrylonitrile and alkyl(meth)-acrylate, and wherein weight ratio of said first grafted phase to said subsequent grafted phase is 1/4 to 4/1, said grafted rubber is present in particulate form having a weight average particle size of about 0.1 to 1.0 microns, and wherein matrix contains the polymerized product of at least one vinylaromatic monomer and at least one monomer selected from the group consisting of (meth)acrylonitrile and alkyl(meth)acrylate, said first grafted phase and said subsequent grafted phase being chemically different one from the other.
A thermoplastic molding composition comprising
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