Processes for the preparation of metallocene complexes
AssigneeChisso Corporation
InventorsHiroshi Yamazaki, Masato Nakano, Seiki Mitani, Jun Saito, Masato Harada, Mina Koyama
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Abstract
Disclosed is a process for the preparation of metallocone complexes wherein stereoisomers of metallocene complexes formed at the time of synthesis can easily be separated. The gist of the present invention resides in separation of a part of an isomeric mixture of specific metallocene complexes bridged with a transition metal represented by the formula (1) as a complex having M—O bond. In particular, preferable is a process for separating a part of an isomeric mixture of a metallocene complex represented by the formula (2) as a μ-oxo-complex represented by the formula (3).
Claims6
A process for the preparation of metallocene complexes which comprises converting a part of an isomeric mixture of a metallocene complex represented by the formula (1):
- wherein M stands for a transition metal belonging Group III, IV, V, VI, Lantanoid or Actinoid of the Periodic Table, n stands for an integer of 1 or 2, Y stands for carbon, silicon, germanium or tin, X's may be the same or different and each independently stands for a halogen atom, a halogenoid atomic group, a hydrocarbon group having 1-20 carbon atoms which may contain a silicon, germanium, oxygen, sulfur, or nitrogen, or a monocyclic or polycyclic heteroaromatic group which may contain a hetero atom or atoms selected from the group consisting of oxygen atoms, sulfur atoms and nitrogen atoms in the 5-membered or 6-membered ring or rings thereof and which may be substituted on the ring or rings thereof by other substituents, R1, R2, R3, R4, R5, R6, R7, R8, R9 and R10 may be the same or different and each stands for hydrogen, an alkyl group having 1-20 carbon atoms, a cycloalkyl group having 3-20 carbon atoms, an alkenyl group with 2-20 carbon atoms, an aryl group having 6-20 carbon atoms, an alkylaryl group having 7-20 carbon atoms, or an aralkyl group having 7-20 carbon atoms with the proviso that these groups may contain a silicon, germanium, oxygen, sulfur, or nitrogen, or a monocyclic or polycyclic heteroaromatic group which may contain a hetero atom or atoms selected from the group consisting of oxygen atoms, sulfur atoms and nitrogen atoms in the 5-membered or 6-membered ring or rings thereof and which may be substiututed on the ring or rings by other substituents with the proviso that the adjacent substituents on the cyclopentadienyl groups may form together a cyclic structure having 5-8 carbon atoms and the cyclic structure may be an aromatic ring, and that R9 and R10 may form together with Y a cyclic structure having 4-8 atoms and which may contain oxygen, sulfur and nitrogen, into a complex containing M—O bond, and then separating it.
A process for the preparation of metallocene complexes which comprises converting a part of an isomeric mixture of a metallocene complex represented by the formula (2):
- wherein M stands for titanium, zirconium or hafnium, n stands for an integer of 1 or 2, Y stands for carbon, silicon or germanium, X's may be the same or different and each independently stands for a halogen atom, a halogenoid atomic group, a hydrocarbon group having 1-20 carbon atoms which may contain a silicon, germanium, oxygen, sulfur, or nitrogen, R2 and R7 may be the same or different and each stands for an alkyl group having 1-20 carbon atoms, a cycloalkyl group having 3-20 carbon atoms, an alkenyl group having 2-20 carbon atoms, an aryl group having 6-20 carbon atoms, an alkylaryl group having 7-20 carbon atoms, or an aralkyl group having 7-20 carbon atoms which may include silicon, germanium, oxygen, sulfur and nitrogen, R1, R4, R5, and R8 may be the same or different and each stands for hydrogen, an alkyl group having 1-20 carbon atoms, a cycloalkyl group having 3-20 carbon atoms, an alkenyl group having 2-20 carbon atoms, an aryl group having 6-20 carbon atoms, an alkylaryl group having 7-20 carbon atoms, an aralkyl group having 7-20 carbon atoms which may include silicon, germanium, oxygen, sulfur, and nitrogen, or a monocyclic or polycyclic heteroaromatic group which may contain a hetero atom or atoms selected from the group consisting of oxygen atoms, sulfur atoms and nitrogen atoms in the 5-membered or 6-membered ring or rings thereof and which may be substituted on the ring or rings by other substituents with the. proviso that R1 and R2 as well as R7 and R8 may form together a cyclic structure having 5-8 carbon atoms which may be an aromatic ring, and that R7 and R8 may form together a cyclic structure having 4-8 carbon atoms which may include oxygen, sulfur and nitrogen, into a μ-oxo-complex represented by the formula (3).
- and then separating the μ-oxo-complex.
A process for the preparation of metallocene complexes which comprises converting a part or the total amount of a meso form out of a mixture of the meso form and a racemic form of a metallocene complex represented by the aforesaid formula (2) into a μ-oxo-complex represented by the aforesaid formula (3) and then separating the μ-oxo-complex.
A process for the preparation of metallocene complexes which comprises reacting a mixture of a meso form and a racemic form of a metallocene complex represented by the aforesaid formula (2) wherein X stands for a halogen atom with water in the presence of a base thereby converting a part or the total amount of the meso form into a μ-oxo-complex represented by the aforesaid formula (3) and then separating the μ-oxo-complex.
Dependencies are inferred from the claim text.