Substantially water-insoluble cationized solids, and their preparation and use
AssigneeClariant GmbH
InventorOliver Eyrisch
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AssigneeClariant GmbH
InventorOliver Eyrisch
Estimating the term…
The present invention relates to water-insoluble cationized solids obtained by treating solids with cationic homopolymers and/or copolymers comprising allylic and/or vinylic double bonds, where cationization is carried out using nitrogen-containing cationic polymers and/or copolymers which comprise from 0.5 to 100 mol-%, preferably from 5 to 20 mol-%, of said double bonds, based on nitrogen equivalents. The invention relates in particular to cationized solids obtained by cationization with allylated and/or vinylated derivatives of amino-containing polymers and/or copolymers. The invention also embraces the preparation of cationized solids by free-radical crosslinking of the abovementioned cationic polymers and/or copolymers in the presence of solids. The products obtained are in general at least 95% insoluble in water. They are obtained by cationizing mineral materials and, preferably, cellulose and are used preferably as retention aids and/or fixing agents in papermaking.
A substantially water-insoluble cationized solid obtained by treating a solid with a nitrogen-containing cationic polymer and/or copolymer, said polymer and/or copolymer contains structural units from 1,1-diallyl-3,4-dimethylenepyrrolidinium, and which comprises from 0.5 to 100 mol-% of allylic and/or vinylic double bonds, based on nitrogen equivalents.
Substantially water-insoluble cationized solids selected from the group consisting of mineral substances, cellulose, clay minerals, granular particles, fiberlike particles, films and textiles, obtained by treating said solids with a nitrogen-containing cationic polymer and/or copolymer, said polymer and/or copolymer contains structural units from 1,1-diallyl-3,4-dimethylenepyrrolidinium, and which comprises from 0.5 to 100 mol-% of allylic and/or vinylic double bonds, based on nitrogen equivalents.
Dependencies are inferred from the claim text.