Process for treating water-containing natural gas wells and natural gas storage wells

A process for treating water-containing natural gas wells and natural gas storage wells in which a homogeneous phase comprising a water-repellant, solvolysis-resistant active compound is injected into the water-bearing rock, wherein said water repellant, solvolysis-resistant active compound is a combination of solvent-soluble organosilicon compound dissolved in solvent, the organosilicon compound and solvent combinations selected from the group consisting of

• a) organosilicon compounds containing units of the formula A a ⁢ R b ⁢ SiO ( 4 - ( a + b ) ) 2
• where
• R denotes a hydrogen atom or a monovalent, divalent or trivalent hydrocarbon radical having 1 to 200 carbon atoms, which can be substituted by halogen, amino, ammonium, mercapto, acrylate or maleimide groups,
• A is —NR5R5
• R5 denotes a hydrogen atom or a hydrocarbon radical having 1 to 200 carbon atoms per radical, which can be interrupted by one or more groups of the formulae —C(O)—, —C(O)O—, —C(O)NR5—, —NR5—, —N+HR5—, —N+R5R5—, —O— or —S—, optimally substituted by F, Cl or Br,
• a is 0, 1 or 2,
• b is 1, 2, or 3,
• with the proviso that at least one A is present per molecule, the sum of a+b is less than 4 and the solvent is an alcohol, a glycol, or a glycol ether;
• b) organosilicon compounds containing units of the formula R b ⁢ SiX c ⁢ O ( 4 - ( b + c ) 2
• wherein R is as defined above,
• X is —OR1
• where
• R1 denotes a hydrogen atom or a hydrocarbon radical having 1 to 200 carbon atoms, optionally interrupted by one or more identical or different heteroatoms which are selected from the group consisting of O, S, N and P,
• or where X is —[OCH(CH3)CH2]e[OCH2CH2]f[O(CH2)4]gOR3
• where R3 is R1 or a radical of the formula —C(O)R1 or —Si(R1)3
• b is 0, 1, 2, or 3,
• c is 0, 1, or 2, and
• e, f, and g independently are integers from 0 to 200 with the proviso that the sum of e+f+g>1, and
• the sum of b and c is less than 4, with the proviso that there is at least one X per molecule, and a hydrocarbon solvent, and
• c) a methylhydrogen organopolysiloxane and a hydrocarbon solvent.