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US 6,150,572 AGranted
Process for the regeneration of a catalyst based on trivalent chromium compounds
AssigneeAusimont S.p.A.
InventorsFrancesco Rinaldi, Paolo Cuzzato, Letanzio Bragante
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Abstract
Process for the regeneration of a fluorination catalyst based on Cr(III) compounds optionallay supported comprising a) the treatment at 350.degree. C.-400.degree. C. with an air/inert gas mixture and b) treatment at 300.degree. C.-380.degree. C. with a mixture of an inert gas containing from 1 to 10% by volume of hydrogen.
Claims1
A process for fluorinating halogen-containing hydrocarbons with HF in a gaseous phase in the presence of a catalyst, based on Cr(III) compounds optionally supported, said catalyst being regenerated by the steps comprising:
- a) treating the exhausted catalyst with a flow of air or of an oxygen/inert gas mixture, at temperatures from 350.degree. C. to 400.degree. C., until the organic contaminants disappear, and
- b) treating the catalyst obtained after phase a) for a time less than 1 hour with a flow of a gaseous mixture formed by an inert gas and from 3 to 6% by volume of hydrogen, at temperatures from 310 to 340.degree. C. until complete disappearance of the Cr (VI) compounds formed during the oxidation phase a).
Dependencies are inferred from the claim text.