Electrical devices including ethylene, .alpha.-olefin, vinyl norbornene elastomers and ethylene .alpha.-olefin polymers
AssigneeExxon Chemical Patents Inc.
InventorsNarayanaswami Raja Dharmarajan, Periagaram Srinivasan Ravishankar, Charles Douglas Burrage
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Abstract
Elastomeric polymers including ethylene, alpha-olefin and vinyl norbornene are shown to have improved extrusion characteristics, improved electrical properties, improved cure characteristics compared to ethylene, alpha-olefin, non-conjugated diene elastomeric polymers containing non-conjugated dienes other than vinyl norbornene. The elastomeric polymers containing vinyl norbornene generally have a branching index below 0.5. Such elastomeric polymers are combined with metallocene catalyzed ethylene, alpha-olefin copolymers to improve physical properties.
Claims1
A power cable coating compound comprising an ethylene, alpha-olefin, vinyl norbornene elastomeric polymer and an ethylene alpha-olefin copolymer said copolymer wherein:
- a) said elastomeric polymer has a BI less than about 0.4, an ethylene content in the range of 50-90 mole percent, a vinyl norbornene content in the range of 0.16-1.5 mole percent, and a M.sub.w /M.sub.n greater than about 10;
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- b) said ethylene alpha-olefin copolymer has a M.sub.w /M.sub.n less than about 3, a CDBI greater than about 60% wherein a compound including said elastomeric polymer and said ethylene alpha-olefin copolymer has a cure rate above about 100 dN.m/min, a cure state above about 90 dN.m/min, a tensil strength above about 9 MPa and an elongation above about 250%.
Dependencies are inferred from the claim text.