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US 6,147,271 AGranted
Oligomerization process
AssigneeBP Amoco Corporation
InventorsAllen David Strebel, Jeffrey Robert Wolf, William Lee Cox
Life of this patent
Estimating the term…
Abstract
A process for oligomerizing an acyclic monoolefin monomer in which the oligomerization is controlled to produce predetermined relative amounts of at least two preselected oligomers in a higher boiling fraction of the oligomerization products and the lower boiling products are recycled to the oligomerization reaction.
Claims12
A process for producing a synthetic hydrocarbon having a predetermined composition comprising:
- oligomerizing an acyclic monoolefin monomer having from 6 to 30 carbon atoms in the presence of a recycled fraction and an oligomerization catalyst system, under conditions of reaction temperature, pressure, catalyst system composition and concentration and reaction time that are selected such that the ratio of the concentrations of at least two preselected oligomers in the mixture of oligomers produced having molecular weights at least as large as the lowest molecular weight of such preselected oligomers is within a predetermined range of values therefor, and the combined concentration of such at least two preselected oligomers comprises at least about 60 weight percent of those oligomers produced having molecular weights at least as large as the lowest molecular weight of such preselected oligomers;
- separating the catalyst from the product mixture and terminating the oligomerization either before the ratio of the aforesaid concentrations of the aforesaid at least two preselected oligomers falls outside the predetermined range of values therefor or before the combined concentration of such at least two preselected oligomers comprises less than about 60 weight percent of those oligomers produced having molecular weights at least as large as the lowest molecular weight of such at least two oligomers;
- separating the oligomerization product mixture into (a) a lower boiling fraction comprising unreacted monomer, oligomers having lower molecular weights than the lowest molecular weight of such preselected oligomers, and optionally a minor portion of oligomers having molecular weights at least as large as the lowest molecular weight of the preselected oligomers and (b) a higher boiling fraction as the synthetic hydrocarbon product and comprising at least a major portion of the oligomers having molecular weights at least as large as the lowest molecular weight of the preselected oligomers and
- recycling to the oligomerization step at least a portion of the separated aforesaid lower boiling point fraction as the aforesaid recycled fraction.
1 more element
Dependencies are inferred from the claim text.