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US 6,147,134 AGranted
Process for preparing rigid and flexible polyurethane foams
AssigneeImperial Chemical Industries PLC
InventorBerend Eling
Life of this patent
Estimating the term…
Abstract
Process for preparing a rigid and a flexible polyurethane foam by reacting a polyisocyanate and two different polyols under foam forming conditions, the polyisocyanate being reacted with said polyols in the absence of compounds comprising primary, secondary or tertiary amines. Flexible foams are obtained which do not show a major glass transition temperature between -100.degree. C. and +25.degree. C.
Claims29
Process for preparing a rigid polyurethane foam by reacting
- a polyisocyanate (1),
- a polyether polyol (2) having a hydroxyl number of at least 150 mg KOH/g and an average nominal hydroxyl functionality of from 2 to 8,
- a polyether polyol (3) having an average equivalent weight of 1000-3000, a hydroxyl number of from 10 to less than 150 mg KOH/g, an average nominal hydroxyl functionality of 2-3 and the structure
- HO--(EO).sub.x --(PO).sub.z --(EO).sub.y --X(--O--(EO).sub.y --(PO).sub.z --(EO).sub.x H).sub.n
- wherein EO is an ethylene oxide radical, PO is a propylene oxide radical x=1-15, y=0-6, z is such so as to arrive at the above equivalent weight, n is 1-2 and X is a hydrocarbon radical having 2-10 carbon atoms or a radical having the formula --CH.sub.2 --CH.sub.2 --(O--CH.sub.2 --CH.sub.2).sub.1-2 --, and
- water
- wherein the amount of polyisocyanate (1), polyol (2), polyol (3) and water is 55-80, 3-20, 10-30, and 2-6 parts by weight respectively per 100 parts by weight of polyisocyanate (1), polyol (2), polyol (3) and water and wherein the reaction is conducted at an isocyanate index of 102-200 and wherein the polyisocyanate is reacted with one or more isocyanate-reactive compositions comprising one or more of the aforementioned polyol (2), polyol (3) and water and not comprising compounds which have a primary, secondary or tertiary nitrogen atom.
4 more elements
Reaction system comprising
- a polyisocyanate (1),
- a polyether polyol (2) having a hydroxyl number of at least 150 mg KOH/g and an average nominal hydroxyl functionality of from 2 to 8,
- a polyether polyol (3) having an average equivalent weight of 1000-3000, a hydroxyl number of from 10 to less than 150 mg KOH/g, an average nominal hydroxyl functionality of 2-3 and the structure
- HO--(EO).sub.x --(PO).sub.z --(EO).sub.y --X(--O--(EO).sub.y --(PO).sub.z --(EO).sub.x H).sub.n
- wherein EO is an ethylene oxide radical, PO is a propylene oxide radical, x=1-15, y=0-6, z is such so as to arrive at the above equivalent weight, n is 1-2 and X is a hydrocarbon radical having 2-10 carbon atoms or a radical having the formula --CH.sub.2 --CH--(O--CH.sub.2 --CH.sub.2).sub.1-2 --, and
- water
- wherein the amount of polyisocyanate (1), polyol (2), polyol (3) and water is 55-80, 3-20, 10-30, and 2-6 parts by weight respectively per 100 parts by weight of polyisocyanate (1), polyol (2), polyol (3) and water and wherein the amount is such that the isocyanate index of 102-200 and wherein the aforementioned polyol (2), polyol (3) and water are not comprising compounds which have a primary, secondary or tertiary nitrogen atom.
4 more elements
Dependencies are inferred from the claim text.