A process for making low k silicon oxide dielectric material having a dielectric constant no greater than 3.0 which comprises reacting organo-silane and hydrogen peroxide reactants in a reactor chamber containing a substrate support with a silicon substrate thereon at a ratio of organo-silane reactant to hydrogen peroxide reactant which will suppress pressure spikes during the formation of said low k silicon oxide dielectric material, and while maintaining an electrical bias potential on said substrate support to thereby form low k silicon oxide dielectric material having a dielectric constant no greater than 3.0 while suppressing pressure spikes.