Coatings based on thermoplastic polyesters with addition of an unsaturated polyester as additive resin
AssigneeHuels Aktiengesellschaft
InventorsRainer Spittka, Hans-Dieter Zagefka, Dirk Hoppe
Life of this patent
Estimating the term…
Abstract
A coating formulation comprises (A) a base polyester consisting of the copolymerization product of at least one aliphatic, cycloaliphatic and/or aromatic polybasic acid and/or anhydride thereof or at least one hydroxycarboxylic acid or derivative thereof and at least one diol, and (B) an additive polyester resin prepared by condensing at least one unsaturated dicarboxylic acid and optionally at least one saturated dicarboxylic acid monomer with at least one diol and/or triol, wherein the proportion of unsaturated additive polyester to base polyester ranges from 0.1-15 parts to 99.9-85 parts.
Claims16
A coating formulation consisting of:
- A) a thermoplastic base polyester consisting of the copolymerization product of at least one aliphatic, cycloaliphatic and/or aromatic polybasic acid and/or anhydride thereof or at least one hydroxycarboxylic acid or derivative thereof and at least one diol;
- B) an unsaturated additive polyester resin prepared by condensing at least one unsaturated dicarboxylic acid and optionally at least one saturated dicarboxylic acid monomer with at least one diol and/or triol, wherein the proportion of unsaturated additive polyester to base polyester ranges from 0.1-15 parts to 99.9-85 parts;
- and
- C) at least one substance selected from the group consisting of color pigments, fillers, stabilizers, leveling agents and luster agents.
A coating formulation comprising:
- A) a thermoplastic base polyester consisting of the copolymerization product of at least one aliphatic, cycloaliphatic and/or aromatic polybasic acid and/or anhydride thereof or at least one hydroxycarboxylic acid or derivative thereof and at least one diol;
- B) an unsaturated additive polyester resin prepared by condensing at least one unsaturated dicarboxylic acid and optionally at least one saturated dicarboxylic acid monomer with at least one diol and/or triol, wherein the proportion of unsaturated additive polyester to base polyester ranges from 0.1-15 parts to 99.9-85 parts;
- C) at least one substance selected from the group consisting of color pigments, fillers, stabilizers, leveling agents and luster agents;
- and
- D) a third polyester formed by reacting:
- a) at least one aromatic dicarboxylic acid and at least one aliphatic dicarboxylic acid of 2-36 atoms, or ester-forming derivatives thereof, and
- b) 1,4-butanediol, or 1,4-butanediol with at least one aliphatic diol having 2-36 carbon atoms, wherein
- the third polyester has a glass transition temperature ranging from -50 to 0.degree. C. and a melting range of 140-200.degree. C., and
- the third polyester is incorporated in the coating formulation in an amount of from 2-60% by weight, based on the overall coating formulation.
Dependencies are inferred from the claim text.