Filled Glass fiber separators for batteries and method for making such separators
AssigneeHollingsworth & Vose Company
InventorsGeorge C. Zguris, Frank C. Harmon, Jr.
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AssigneeHollingsworth & Vose Company
InventorsGeorge C. Zguris, Frank C. Harmon, Jr.
Estimating the term…
A multi-layer sheet useful as a separator (10) in a lead acid battery is disclosed. The sheet comprises at least a first layer (12) and a second layer (14) and having been produced by the method consisting of the steps of forming the first layer (12) by depositing a first, substantially binder free furnish consisting essentially of glass fibers onto the wire (36) of a paper making machine (30) and forming the second layer (14) by depositing a second, substantially binder free furnish consisting essentially of glass fibers and silica powder or another suitable silicate powder onto the first layer (12) on the wire (36) of the paper making machine (30). The silica or silicate powder has a particle size and being present in the second layer (14) in an amount such that, if the second substantially binder free furnish was deposited directly on the wire (36) of the paper making machine (30) a significant portion of the silica or silicate powder would pass through the wire (36).
A sheet useful as a separator in a valve regulated lead acid battery, said sheet comprising at least a first layer of substantially binder free glass fibers and a second layer of substantially binder free glass fibers and a powder that is inert to battery reactions and to materials that are present in batteries, said sheet being produced by the method consisting of the steps of
A multi-layer sheet useful as a separator in a lead acid battery, said sheet comprising a first layer and a second layer, said first layer being substantially binder free, and consisting essentially of glass fibers, and said second layer being substantially binder free and consisting essentially of glass fibers and a powder that is inert to battery reactions and to materials that are present in batteries, said powder having a mean particle size ranging from 0.001 .mu.m to 20 .mu.m, said powder having a particle size and density, and being present in said second layer in an amount such that a significant portion of the powder from a layer formed by depositing the second furnish onto the wire of a paper making machine would pass through the wire, and said first layer having a sufficiently small pore size that substantially all of the powder in said second furnish either remains in a layer formed by depositing the second furnish on the first layer, while on the wire of the paper making machine, or is filtered from the liquid of said furnish by the fibers of the first layer while on the wire of the paper making machine, and substantially all of the powder in the second furnish is retained in the sheet.
A method for producing a sheet useful as a separator in a valve regulated lead acid battery, said method consisting of the steps of depositing a first, substantially binder free furnish consisting essentially of glass fibers onto the wire of a paper making machine to form a first layer and depositing onto the fibers from the first furnish while they are on the wire of the paper making machine a second, substantially binder free furnish consisting essentially of glass fibers and a powder that is inert to battery reactions and to materials that are present in batteries, said powder having a mean particle size ranging from 0.001 .mu.m to 20 .mu.m to form a second layer,
Dependencies are inferred from the claim text.