NO.sub.x reduction compositions for use in FCC processes
AssigneeW. R. Grace & Co.-Conn.
InventorsAlan W. Peters, John A. Rudesill, Gordon Dean Weatherbee, Edward F. Rakiewicz, Mary Jane A. Barbato-Grauso
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AssigneeW. R. Grace & Co.-Conn.
InventorsAlan W. Peters, John A. Rudesill, Gordon Dean Weatherbee, Edward F. Rakiewicz, Mary Jane A. Barbato-Grauso
Estimating the term…
Compositions comprising a component containing (i) an acidic oxide support, (ii) an alkali metal and/or alkaline earth metal or mixtures thereof, (iii) a transition metal oxide having oxygen storage capability, and (iv) a transition metal selected from Groups Ib and/or IIb of the Periodic Table provide NO.sub.x control performance in FCC processes. The acidic oxide support preferably contains silica alumina. Ceria is the preferred oxygen storage oxide. Cu and Ag are preferred Group I/IIIb transition metals. The compositions are especially useful in the cracking of hydrocarbon feedstocks having above average nitrogen content.
A NOx removal composition suitable for reducing NOx emissions in the presence of a CO oxidation promoter during catalyst regeneration in a fluid catalytic cracking process, said composition comprising particles having a particle size of about 20-200 .mu.m and consisting essentially of (i) an acidic oxide support containing at least 50 wt % alumina, (ii) about 1-10 parts by weight of magnesium oxide;
A fluid cracking catalyst comprising (a) a cracking component suitable for catalyzing the cracking of hydrocarbons, and (b) a NOx reduction component consisting essentially of (i) an acidic oxide support containing at least 50 wt % alumina, (ii) about 1-10 parts by weight of magnesium oxide;
A method of reducing NOx emissions in the presence of CO oxidation promoters during fluid cracking of a hydrocarbon feedstock into lower molecular weight components, said method comprising contacting a hydrocarbon feedstock with a cracking catalyst at elevated temperature whereby lower molecular weight hydrocarbon components are formed, said cracking catalyst comprising (a) a cracking component suitable for catalyzing the cracking of hydrocarbons, and (b) a NOx reduction component consisting essentially of (i) an acidic oxide support containing at least 50 wt % alumina, (ii) about 1-10 parts by weigh of magnesium oxide;
Dependencies are inferred from the claim text.