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US 6,140,478 AGranted
Basic azo compounds, their production and use
AssigneeClariant Finance (BVI) Limited
InventorsJurgen Geiwiz, Helmut Anton Moser, Reinhard Pedrazzi
Life of this patent
Estimating the term…
Abstract
Basic azo compounds of formula I are suitable for coloring or printing especially of paper and leather.
Claims12
A basic azo compound of formula I ##STR36## wherein the two Rs independently of each other are H, C.sub.1-4 alkyl, C.sub.5-6 cycloalkyl, phenyl, benzyl or phenylethyl,
- T.sub.1 and T.sub.2 independently of each other are H, --CN, --COOR.sub.5, CONR.sub.6 R.sub.7, SO.sub.2 NR.sub.6 R.sub.7, ##STR37## R.sub.1 signifies C.sub.1-6 alkylene or C.sub.2-6 alkenylene, R.sub.2 and R.sub.3 independently of each other are unsubstituted C.sub.1-6 alkyl, C.sub.2-6 alkyl substituted by OH, CN or halogen, phenyl-C.sub.1-3 alkyl, wherein the phenyl radical is optionally substituted from 1 to 3 times, by chlorine, C.sub.1-4 alkyl or C.sub.1-4 alkoxy, unsubstituted C.sub.5-6 cycloalkyl or C.sub.5-6 cycloalkyl substituted from 1 to 3 times by C.sub.1-4 alkyl groups,
- R.sub.4 signifies any of the meanings of R.sub.2 or R.sub.3 or hydrogen,
- R.sub.5 signifies a C.sub.1-6 alkyl radical or phenyl-C.sub.1-3 alkyl radical,
- R.sub.6 and R.sub.7 independently of each other are H or a C.sub.1-4 alkyl radical,
- R.sub.8 independently of each other signifies H, a C.sub.1-4 alkyl radical, --NR.sub.6 R.sub.7 or --CONR.sub.6 R.sub.7,
- R.sub.9 signifies a C.sub.1-4 alkyl radical or a hydroxy-C.sub.1-4 alkyl radical,
- R.sub.10 signifies --S--, --O-- or ##STR38## R.sub.11 signifies hydrogen or a C.sub.1-4 alkyl radical, the two R.sub.12 's independently of each other, are halogen, OH, a C.sub.1-4 alkyl radical or a C.sub.1-4 alkoxy radical,
- the two m's independently of each other, are 0, 1 or 2,
- X signifies:
- X.sub.1 a direct bond;
- X.sub.2 a straight or branched C.sub.1-4 alkylene;
- X.sub.3 --NH--CS--NH--;
- X.sub.4 --O--;
- X.sub.5 --CH.dbd.CH--;
- X.sub.6 --*NH--CO--;
- X.sub.6a --NH--*CO--;
- X.sub.7 ##STR39## wherein the asterixed atom is bonded to ring D.sub.1 ;
- ##STR40## R.sub.13 is halogen, a C.sub.1-4 alkyl radical or a C.sub.1-4 alkoxy radical,
- R.sub.14 is straight or branched C.sub.1-4 -alkylene,
- the two R.sub.15 S independently of each other, are H or a C.sub.1-4 alkyl radical,
- R.sub.16 is halogen, --NHCH.sub.2 CH.sub.2 OH, --N(CH.sub.2 CH.sub.2 OH).sub.2, NH.sub.2, OH or --NH(CH.sub.2).sub.2-3 N(C.sub.2 H.sub.5).sub.2,
- A.sup.- is an anion, or
- mixtures of two or more of the above compounds.
20 more elements
A process for the preparation of the compounds of formula I wherein a diamine of formula II is coupled with a coupling component of formulae III and IV ##STR44##
Dependencies are inferred from the claim text.