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US 6,139,623 AGranted
Emulsified comb polymer and defoaming agent composition and method of making same
AssigneeW. R. Grace & Co.-Conn.
InventorsDavid Charles Darwin, Robert T. Taylor, Ara A. Jeknavorian, Ding Feng Shen
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Abstract
Exemplary emulsion admixture for use in hydraulic cement compositions formed by emulsifying an antifoaming agent, surfactant, and a comb polymer having a carbon-containing backbone to which are attached cement-anchoring members and oxyalkylene groups. A method of making a stable emulsion admixture comprising the comb polymer, as well as a hydraulic cement composition comprising the admixture, are also described.
Claims27
An emulsion admixture composition for hydraulic cement compositions, comprising:
- (a) a comb polymer operative as a plasticizer in hydratable cementitious compositions, said comb polymer having a carbon-containing backbone to which are attached pendant cement-anchoring members and oxyalkylene members, said oxyalkylene members comprising ethylene oxide groups, propylene oxide groups, or a mixture thereof, said comb polymer being in the amount of 80-98.9 dry wt. % dry based on solids content of the emulsion admixture;
- (b) an antifoaming agent emulsified with said comb polymer, said antifoaming agent in the amount of 1-15 dry wt. % based on solids content of the emulsion admixture, said antifoaming agent being selected from the group consisting of (i) a phosphate ester having the formula P(O)(O--R).sub.3 wherein P represents phosphorus, O represents oxygen, and R represents a C.sub.2 -C.sub.20 alkyl group;
- (ii) a borate ester;
- and (iii) and a polyoxyalkylene copolymer having defoaming properties;
- (c) at least one surfactant in the amount of 0.05-10.0 dry wt. % based on solids content of the emulsion admixture, said at least one surfactant operative to stabilize said emulsion mixture, said surfactant comprising (i) an esterified fatty acid ester of a carbohydrate selected from the group consisting of a sugar, sorbitan, a disaccharide, and a polysaccharide;
- (ii) a C.sub.2 -C.sub.20 alcohol having polyoxyalkylene groups;
- or (iii) a mixture thereof;
- and
- (d) water in the amount of 40 90 wt. % of the emulsion admixture.
6 more elements
Dependencies are inferred from the claim text.