2,4,5-trisubstituted phenylketo-enols for use as pesticides and herbicides

A compound of the formula (I) ##STR171## in which X represents halogen, C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -alkinyl, C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.4 -halogenoalkyl, C.sub.1 -C.sub.4 -halogenoalkoxy, cyano or nitro,

• Y represents halogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, C.sub.l -C.sub.4 -halogenoalkyl, C.sub.1 -C.sub.4 -halogenoalkoxy, cyano or nitro,
• Z represents halogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.4 -halogenoalkyl, C.sub.1 -C.sub.4 -halogenoalkoxy, hydroxyl, cyano or nitro, or phenoxy, phenylthio, thiazolyloxy, pyridinyloxy, pyrimidyloxy, pyrazolyloxy, phenyl-C.sub.1 -C.sub.4 -alkyloxy or phenyl-C.sub.1 -C.sub.4 -alkylthio which are in each case optionally substituted by halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -halogenoalkyl, C.sub.1 -C.sub.4 -halogenoalkoxy, nitro or cyano, or
• Het represents ##STR172## A, B and the carbon atom to which they are bonded represent C.sub.3 -C.sub.10 -cycloalkyl or C.sub.5 -C.sub.10 -cycloalkenyl, wherein one methylene group is optionally replaced by oxygen or sulphur and which are optionally substituted by C.sub.1 -C.sub.8 -alkyl, C.sub.3 -C.sub.10 -cycloalkyl, C.sub.1 -C.sub.8 -halogenoalkyl, C.sub.1 -C.sub.8 -alkoxy, C.sub.1 -C.sub.8 -alkylthio, halogen or phenyl, or
• A, B and the carbon atom to which they are bonded represent C.sub.5 -C.sub.6 -cycloalkyl which is substituted by an alkylenediyl group which optionally contains one or two oxygen and/or sulphur atoms or by an alkylenedioxyl group or by an alkylenedithioyl group, this substituent forming a further five- to eight-membered ring with the carbon atom to which it is bonded, or
• A, B and the carbon atom to which they are bonded represent C.sub.3 -C.sub.8 -cycloalkyl or C.sub.5 -C.sub.8 -cycloalkenyl in which two substituents, together with the carbon atom to which they are bonded, represent C.sub.3 -C.sub.6 -alkanediyl, C.sub.3 -C.sub.6 -alkenediyl or C.sub.4 -C.sub.6 -alkadienediyl which are in each case optionally substituted by C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy or halogen and wherein in each case one methylene group is optionally replaced by oxygen or sulphur,
• G represents hydrogen (a), or represents one of the groups ##STR173## in which E represents one metal ion equivalent or an ammonium ion,
• L represents oxygen or sulphur and
• M represents oxygen or sulphur,
• R.sup.1 represents C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.20 -alkenyl, C.sub.1 -C.sub.8 -alkoxy-C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkylthio-C.sub.1 -C.sub.8 -alkyl or poly-C.sub.1 -C.sub.8 -alkoxy-C.sub.1 -C.sub.8 -alkyl which are in each case optionally substituted by halogen, or represents C.sub.3 -C.sub.8 -cycloalkyl which is optionally substituted by halogen, C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -alkoxy and in which one or two methylene groups are optionally replaced by oxygen and/or sulphur,
• or represents phenyl which is optionally substituted by halogen, cyano, nitro, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.6 -halogenoalkyl, C.sub.1 -C.sub.6 -halogenoalkoxy, C.sub.1 -C.sub.6 -alkylthio or C.sub.1 -C.sub.6 -alkylsulphonyl,
• or represents phenyl-C.sub.1 -C.sub.6 -alkyl which is optionally substituted by halogen, nitro, cyano, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.6 -halogenoalkyl or C.sub.1 -C.sub.6 -halogenoalkoxy,
• or represents 5- or 6-membered hetaryl having one or two heteroatoms from the series consisting of oxygen, sulphur and nitrogen which is optionally substituted by halogen or C.sub.1 -C.sub.6 -alkyl,
• or represents phenoxy-C.sub.1 -C.sub.6 -alkyl which is optionally substituted by halogen or C.sub.1 -C.sub.6 -alkyl or
• represents 5- or 6-membered hetaryloxy-C.sub.1 -C.sub.6 -alkyl which has one or two heteroatoms from the series consisting of oxygen, sulphur and nitrogen and is optionally substituted by halogen, amino or C.sub.1 -C.sub.6 -alkyl,
• R.sup.2 represents C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.20 -alkenyl, C.sub.1 -C.sub.8 -alkoxy-C.sub.2 -C.sub.8 -alkyl or poly-C.sub.1 -C.sub.8 -alkoxy-C.sub.2 -C.sub.8 -alkyl which are in each case optionally substituted by halogen,
• or represents C.sub.3 -C.sub.8 -cycloalkyl which is optionally substituted by halogen, C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -alkoxy, or
• represents phenyl or benzyl which are in each case optionally substituted by halogen, cyano, nitro, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.6 -halogenoalkyl or C.sub.1 -C.sub.6 -halogenoalkoxy,
• R.sup.3 represents C.sub.1 -C.sub.8 -alkyl which is optionally substituted by halogen, or phenyl or benzyl which are in each case optionally substituted by halogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.4 -halogenoalkyl, C.sub.1 -C.sub.4 -halogenoalkoxy, cyano or nitro,
• R.sup.4 and R.sup.5 independently of one another represent C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkoxy, C.sub.1 -C.sub.8 -alkylamino, di-(C.sub.1 -C.sub.8 -alkyl)amino, C.sub.1 -C.sub.8 -alkylthio or C.sub.3 -C.sub.8 -alkenylthio which are in each case optionally substituted by halogen, or represent phenyl, phenoxy or phenylthio which are in each case optionally substituted by halogen, nitro, cyano, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -halogenoalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -halogenoalkylthio, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -halogenoalkyl,
• R.sup.6 and R.sup.7 independently of one another represent hydrogen, or represent C.sub.1 -C.sub.8 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.1 -C.sub.8 -alkoxy, C.sub.3 -C.sub.8 -alkenyl or C.sub.1 -C.sub.8 -alkoxy-C.sub.2 -C.sub.8 -alkyl which are in each case optionally substituted by halogen, or represent phenyl or benzyl which are in each case optionally substituted by halogen, C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -halogenoalkyl or C.sub.1 -C.sub.8 -alkoxy, or together represent a C.sub.3 -C.sub.6 -alkylene radical which is optionally substituted by C.sub.1 -C.sub.6 -alkyl and in which one methylene group is optionally replaced by oxygen or sulphur,
• R.sup.13 represents hydrogen, or C.sup.1 -C.sub.8 -alkyl or C.sub.1 -C.sub.8 -alkoxy which are in each case optionally substituted by halogen, or represents C.sub.3 -C.sub.8 -cycloalkyl which is optionally substituted by halogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy and in which one methylene group is optionally replaced by oxygen or sulphur, or represents phenyl, phenyl-C.sub.1 -C.sub.4 -alkyl or phenyl-C.sub.1 -C.sub.4 -alkoxy which are in each case optionally substituted by halogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.4 -halogenoalkyl, C.sub.1 -C.sub.4 -halogenoalkoxy, nitro or cyano,
• R.sup.14 represents hydrogen or C.sub.1 -C.sub.8 -alkyl, or
• R.sup.13 and R.sup.14 together represent C.sub.4 -C.sub.6 -alkanediyl,
• R.sup.15 and R.sup.16 are identical or different and represent C.sub.1 -C.sub.6 -alkyl, or
• R.sup.15 and R.sup.16 together represent a C.sub.2 -C.sub.4 -alkanediyl radical which is optionally substituted by C.sub.1 -C.sub.6 -alkyl or by phenyl which is optionally substituted by halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -halogenoalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -halogenoalkoxy, nitro or cyano,
• R.sup.17 and R.sup.18 independently of one another represent hydrogen, or represent C.sub.1 -C.sub.8 -alkyl which is optionally substituted by halogen, or represent phenyl which is optionally substituted by halogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.4 -halogenoalkyl, C.sub.1 -C.sub.4 -halogenoalkoxy, nitro or cyano, or
• R.sup.17 and R.sup.18, together with the carbon atom to which they are bonded, represent C.sub.5 -C.sub.7 -cycloalkyl which is optionally substituted by C.sub.1 -C.sub.4 -alkyl and in which one methylene group is optionally replaced by oxygen or sulphur,
• R.sup.19 and R.sup.20 independently of one another represent C.sub.1 -C.sub.10 -alkyl, C.sub.2 -C.sub.10 -alkenyl, C.sub.1 -C.sub.10 -alkoxy, C.sub.1 -C.sub.10 -alkylamino, C.sub.3 -C.sub.10 -alkenylamino, di-(C.sub.1 -C.sub.10 -alkyl)amino or di-C.sub.3 -C.sub.10 -alkenyl)amino.