Process for the electrolytic deposition of metal layers
AssigneeAtotech Deutschland GmbH
InventorsWolfgang Dahms, Heinrich Meyer, Stefan Kretschmer
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AssigneeAtotech Deutschland GmbH
InventorsWolfgang Dahms, Heinrich Meyer, Stefan Kretschmer
Estimating the term…
The invention relates to a method for the electrolytic deposition of metal coatings, in particular of copper coatings with certain physical-mechanical and optical properties and uniform coating thickness. According to known methods using soluble anodes and applying direct current, only uneven metal distribution can be attained on complex shaped workpieces. By using a pulse current or pulse voltage method, the problem of the coatings being of varying thickness at various places on the workpiece surfaces can indeed be reduced. However, the further problem of the geometric ratios being changed continuously during the depositing process by dissolving of the anodes is not resolved thus. This can be avoided by using insoluble anodes. In order to guarantee sufficient stability of the anodes and a bright coating even at those points on the workpiece surfaces, onto which the metal is deposited with high current density, it is essential to add compounds of an electrochemically reversible redox system to the depositing solution.
Method for the electrolytic deposition of fine crystalline metal coatings with uniform distribution of layer thicknesses and uniform brightness, high fracture elongation and tensile strength even in places of high current density, by means of a pulse current method comprising a duration of cathodic, or cathodic and anodic, pulses of current or voltage, comprising the steps of:
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