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US 6,096,918 AGranted
Aryl-acrylic acid esters
AssigneeGivaudan Roure (International) SA
InventorsDenise Anderson, Georg Frater
Life of this patent
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Abstract
The acrylic acid esters of Formula I are useful for the delivery of organoleptic compounds, especially for flavors, fragrances, masking agents and antimicrobial compounds. They can also deliver fluorescent whitening agents.
Claims18
A compound of Formula I ##STR5## wherein A is selected from benzene and naphthalene rings;
- R.sup.1 is a saturated, unsaturated, straight, branched, alicyclic or an aromatic C.sub.10 -C.sub.30 hydrocarbon residue which can contain heteroatoms and can be substituted by an ionic substituent;
- R.sup.2 in 2- or 3-position is a hydrogen, a straight or branched C.sub.1 -C.sub.6 residue, an optionally substituted aromatic or an optionally substituted heterocyclic residue;
- R.sup.3 and R.sup.4 are a hydrogen, a straight or branched C.sub.1 -C.sub.6 alkyl, a C.sub.1 -C.sub.6 alkoxy residue, a substituted or condensed heterocyclic residue, --OH, --NO.sub.2, --NH.sub.2, --N(C.sub.1 -C.sub.6 alkyl).sub.2, --N(hydroxyalkyl).sub.2, --NHCO.sub.2 CH.sub.3 or --NH(heterocycle),
- wherein R.sup.2, R.sup.3 and R.sup.4 are the same or different;
- X is an --OH or NHR.sup.6, wherein R.sup.6 is a hydrogen, a saturated or unsaturated, straight or branched C.sub.1 -C.sub.20 hydrocarbon, or
- an optionally substituted aromatic or heterocyclic residue;
- and the acrylic double bond is of the E configuration.
4 more elements
A method for preparing compositions which provide upon activation organoleptic, antimicrobial or fluorescent whitening properties comprising incorporating into one of these compositions a compound of Formula I:
- ##STR9## wherein A is selected from benzene and naphthalene rings;
- R.sup.1 is a saturated, unsaturated, straight, branched, alicyclic or an aromatic C.sub.10 -C.sub.30 hydrocarbon residue which can contain heteroatoms and can be substituted by an ionic substituent;
- R.sup.2 in the 2- or 3-position is a hydrogen, a straight or branched C.sub.1 -C.sub.6 residue, an optionally substituted aromatic or an optionally substituted heterocyclic residue;
- R.sup.3 and R.sup.4 are a hydrogen, a straight or branched C.sub.1 -C.sub.6 alkyl, a C.sub.1 -C.sub.6 alkoxy residue, a substituted or condensed heterocyclic residue, --OH, --NO.sub.2, --NH.sub.2, --N(C.sub.1 -C.sub.6 alkyl).sub.2, --N (hydroxyalkyl).sub.2, --NHCO.sub.2 CH.sub.3 or --NH (heterocycle);
- wherein R.sup.2, R.sup.3 and R.sup.4 are the same or different;
- X is an --OH or NHR.sup.6, wherein R.sup.6 is a hydrogen, a saturated or unsaturated, straight or branched C.sub.1 -C.sub.20 hydrocarbon, or an optionally substituted aromatic or heterocyclic residue;
- and
- the acrylic double bond is of the E configuration.
5 more elements
Dependencies are inferred from the claim text.