Propylene homopolymer
AssigneeToho Titanium Co., Ltd.
InventorsTakuo Kataoka, Masayoshi Saito
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Abstract
A propylene homopolymer having a high stereo-regularity and an excellent processability during sheet or film formation, characterized in that it exhibits a melt flow rate (MFR) of from 0.1 to 20 g/10 min., a xylene-soluble component content of not more than 6% by weight and an isoblock content [IB] of at least 3 mol % as determined by the following equation (1) from Pmmmr, Pmmrr and Pmrrm, which are absorption intensities attributed to isoblock chain in xylene-insoluble component by .sup.13 C-NMR spectrum: [IB]=[Pmmmr]+[Pmmrr]+[Pmrrm] (1) wherein [Pmmmr], [Pmmrr] and [Pmrrm] are the relative intensity ratio (mol %) of Pmmmr, Pmmrr and Pmrrm, respectively, which are absorption intensities attributed to isoblock chain.
Claims6
A propylene homopolymer, having a melt flow rate (MFR) determined at a temperature of 230.degree. C. under a load of 2.16 kg of from 0.1 to 20 g/10 min., a 23.degree. C. xylene-soluble component content of not more than 6% by weight and an isoblock content [IB] of at least 3 mol % as determined by the following equation (1) from Pmmmr, Pmmrr and Pmrrm, which are absorption intensities attributed to isoblock chain in xylene-insoluble component by .sup.13 C-NMR spectrum:
- [IB]=[Pmmmr]+[Pmmrr]+[Pmrrm] (1)
- wherein [Pmmmr], [Pmmrr] and [Pmrrm] are the relative intensity ratio (mol %) of Pmmmr, Pmmrr and Pmrrm, respectively, which are absorption intensities attributed to isoblock chain.
A propylene homopolymer, obtained by the polymerization of a propylene in the presence of a solid catalyst component (A) comprising as essential components magnesium, titanium, halogen and an electron donor, an organic aluminum compound (B) and an organic silicon compound (C), having a melt flow rate (MFR) determined at a temperature of 230.degree. C. under a load of 2.16 kg of from 0.1 to 20 g/10 min., a 23.degree. C. xylene-soluble component content of not more than 6% by weight and an isoblock content [IB] of at least 3 mol % as determined by the following equation (1) from Pmmmr, Pmmrr and Pmrrm, which are absorption intensities attributed to isoblock chain in xylene-insoluble component by .sup.13 C-NMR spectrum:
- [IB]=[Pmmmr]+[Pmmrr]+[Pmrrm] (1)
- wherein [Pmmmr], [Pmmrr] and [Pmrrm] are the relative intensity ratio (mol %) of Pmmmr, Pmmrr and Pmrrm, respectively, which are absorption intensities attributed to isoblock chain.
A propylene homopolymer, obtained by the polymerization of a propylene in the presence of a catalyst comprising the following components (A), (B) and (C), having a melt flow rate (MFR) determined at a temperature of 230.degree. C. under a load of 2.16 kg of from 0.1 to 20 g/10 min., a 23.degree. C. a xylene-soluble component content of not more than 6% by weight and an isoblock content [IB] of at least 3 mol % as determined by the following equation (1) from Pmmmr, Pmmrr and Pmrrm, which are absorption intensities attributed to isoblock chain in xylene-insoluble component by .sup.13 C-NMR spectrum:
- [IB]=[Pmmmr]+[Pmmrr]+[Pmrrm] (1)
- wherein [Pmmmr], [Pmmrr] and [Pmrrm] are the relative intensity ratio (mol %) of Pmmmr, Pmmrr and Pmrrm, respectively, which are absorption intensities attributed to isoblock chain:
- (A) A solid catalyst component prepared from the following components (a) to (d):
- (a) A magnesium compound represented by the following general formulae:
- Mg(OR.sup.1).sub.2
- wherein R.sup.1 represents a C.sub.1-4 alkyl group or an aryl group;
- (b) An aluminum compound represented by the following general formulae:
- Al(OR.sup.2).sub.m X.sup.1.sub.3-m
- wherein R.sup.2 represents a C.sub.1-4 alkyl group or an aryl group;
- X.sup.1 represents a halogen atom;
- and
- m represents a real number of from at least 0 to not more than 3;
- or
- R.sup.3.sub.n AlX.sup.2.sub.3-n
- wherein R.sup.3 represents a C.sub.1-4 alkyl group;
- X.sup.2 represents a hydrogen atom or halogen atom;
- and
- n represents a real number of from more than 0 to not more than 3;
- (c) A titanium compound represented by the following general formula:
- Ti(OR.sup.4).sub.p X.sup.3.sub.4-p
- wherein R.sup.4 represents a C.sub.1-4 alkyl group;
- X.sup.3 represents a halogen atom;
- and p represents 0 or an integer of from 1 to 3;
- and
- (d) A diester of aromatic dicarboxylic acid;
- (B) An organic aluminum compound represented by the following general formula:
- R.sup.5.sub.q AlY.sub.3-q
- wherein R.sup.5 represents a C.sub.1-4 alkyl group;
- Y represents any one of hydrogen atom, chlorine atom, bromine atom and iodine atom;
- and q represents a real number of from more than 0 to not more than 3;
- and
- (C) An organic silicon compound represented by the following general formula:
- R.sup.6.sub.r Si(OR.sup.7).sub.4-r
- wherein R.sup.6 's may be the same or different and each represents a C.sub.1-12 alkyl group, a cycloalkyl group, a phenyl group, a vinyl group, an allyl group or an aralkyl group;
- R.sup.7 's may be the same or different and each represents a C.sub.1-4 alkyl group, a cycloalkyl group, a phenyl group, a vinyl group, an allyl group or an aralkyl group;
- and r represents 0 or an integer of from I to 3.
Dependencies are inferred from the claim text.