Foamed particles of modified polypropylene resin and method of preparing same
AssigneeJsp Corporation
InventorsHidehiro Sasaki, Masakazu Sakaguchi, Hisao Tokoro
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AssigneeJsp Corporation
InventorsHidehiro Sasaki, Masakazu Sakaguchi, Hisao Tokoro
Estimating the term…
A foamed, non-crosslinked resin particle having a bulk density of not greater than 0.045 g/cm.sup.3 and an average cell diameter of at least 200 .mu.m. The non-crosslinked resin includes a polypropylene resin to which a vinyl comonomer is graft-polymerized in such an amount that the weight ratio of the polypropylene resin to the grafted polymer of the vinyl comonomer is in the range of 97:3 to 65:35. The foamed resin particles are produced by grafting a vinyl comonomer to polypropylene resin particles at a temperature of less than 90.degree. C. in the presence of a specific radical polymerization initiator to obtain modified polypropylene resin particles and, then, expanding the modified polypropylene resin particles. The initiator used requires a temperature of not higher than 70.degree. C. for obtaining a half life of 10 hours.
A foamed, non-crosslinked resin particle having a bulk density of not greater than 0.045 g/cm.sup.3 and an average cell diameter of at least 200 .mu.m, said non-crosslinked resin comprising a polypropylene resin to which a vinyl comonomer is graft-polymerized in such an amount that the weight ratio of said polypropylene resin to said grated polymer of said vinyl comonomer is in the range of 97:3 to 65:35, wherein said foamed, non-crosslinked resin particle has a melting point of at least 125.degree. and a DSC curve by differential scanning calorimetry that includes at least two endothermic Peaks and wherein the highest of the at least two endothermic peaks has an area corresponding to the calorific value of 2-25 J/g when the modified polypropylene resin has a melting point of 150.degree. C. or less or 5-40 J/g when the modified polypropylene resin has a melting point of more than 150.degree. C.
A method of producing foamed, non-crosslinked resin particles, having a melting point of at least 125.degree. C. comprising the steps of:
Dependencies are inferred from the claim text.