Pesticidal compounds
AssigneeBTG International Limited
InventorsBhupinder Pall Singh Khambay, Duncan Batty
Life of this patent
Estimating the term…
Loading patent…
AssigneeBTG International Limited
InventorsBhupinder Pall Singh Khambay, Duncan Batty
Estimating the term…
Pesticidal as a pesticide against whitefly, Lepidoptera and certain fungi is provided of compound of general formula (I) ##STR1## or a salt thereof is provided, in which n represents an integer from 0 to 4; m represents an integer 0 or 1; each R independently represents a halogen atom or a nitro, cyano, hydroxyl, alkyl, alkenyl, haloalkyl, haloalkenyl, alkoxy, haloalkoxy, haloalkenoxy, amino, alkylamino, dialkylamino, alkoxycarbonyl, carboxyl, alkanoyl, alkylthio, alkylsulphinyl, alkylsulphonyl, carbamoyl, alkylamido, cycloalkyl, aryl or aralkyl group; R.sup.1 and R.sup.2 each independently represent an optionally substituted alkoxy group or together represent a group .dbd.O, .dbd.S or .dbd.N--OR.sup.9, where R.sup.9 represents a hydrogen atom or an optionally substituted alkyl group; R.sup.3 represents a hydroxyl group, or a group --OL where L is a leaving group, or a group which in vivo is transformed into a group --OL.sup.1 where L.sup.1 is a leaving group; R.sup.7 and R.sup.8 independently represent an optionally substituted alkoxy group or together represent a group .dbd.O, .dbd.S or .dbd.N--OR.sup.9, where R.sup.9 is as previously defined; wherein R.sub.4 and R.sub.5 independently represent a halogen atom or an optionally substituted alkyl or alkenyl group, or together with the interjacent carbon atom represent an optionally substituted cycloalkyl or cycloalkenyl ring; and A represents a straight or branched chain alkyl or alkenyl group, which may be optionally substituted, an acyclic carbon chain of which links the 3 position of the naphthalene ring shown and the moiety --CHR.sup.4 R.sup.5 and wherein A does not include a quaternary carbon atom in that chain; and wherein the total number of carbon atoms in the longest carbon chain running from the 3-position of the naphthalene ring shown is no more than 8.
A method of combating white fly or Lepidoptera pests at a locus, which comprises treating the locus with a compound of formula (I) ##STR18## or a salt thereof, in which n represents an integer from 0 to 4;
A process for the preparation of a compound of formula (I) comprising reacting an aldehyde corresponding to the group --A--CHR.sup.4 R.sup.5, where --A-- has an aldehyde group at its free end, directly with a compound of formula (V) wherein ##STR24## wherein R, R.sup.3 and n are as defined in formula I, in a polar organic solvent under alkaline conditions, and heating the product under acidic conditions in a non-polar solvent to effect elimination of water.
A process for the preparation of the compound of formula (I) comprising reacting a compound of the formula (V) ##STR25## in which R, R.sup.3 and n are defined above, with a carboxylic acid CHR.sup.4 R.sup.5 --(A).sub.m --COOH where R.sup.4, R.sup.5, m and A are as defined above, in the presence of a free radical initiator.
A process for the preparation of a compound of formula (I) comprising reacting a compound of formula (V) with a compound of formula X--(A).sub.m CHR.sup.4 R.sup.5 wherein X is a leaving group that will leave the compound to give a charged radical .sup.+ (A).sub.m --CHR.sup.4 R.sup.5 in the presence of an acid.
2-hydroxy-3-(2-methylcyclohexyl)-naphthalene-1,4-dione.
2-hydroxy-3-(3-methylcyclohexyl)-naphthalene-1,4-dione.
2-hydroxy-3-(4-methylcyclohexyl)-naphthalene-1,4-dione.
2-hydroxy-3-(4-t-butylcyclohexyl)-naphthalene-1,4-dione.
Dependencies are inferred from the claim text.