Hydrocarbon conversion processes using crystalline manganese phosphate compositions
AssigneeUop LLC
InventorsGregory J. Lewis, Paula L. Bogdan
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Abstract
Hydrocarbon conversion processes using a new family of crystalline manganese phosphate compositions is disclosed. These compositions have an extended network; which network can be a one-, two-, or three-dimensional network. The composition has an empirical formula of: (A.sup.a+).sub.v (Mn.sup.b+)(M.sup.c+).sub.x P.sub.y O.sub.z where A is a templating agent such as an alkali metal, M is a metal such as Al, Fe.sup.3+ and "b" is the average manganese oxidation state and varies from greater than 3.0 to about 4.0.
Claims13
A hydrocarbon conversion process comprising contacting a hydrocarbon feed with a crystalline manganese phosphate composition under hydrocarbon conversion conditions to give a converted product, the manganese phosphate composition having an extended network and an empirical composition on an anhydrous basis expressed by an empirical formula of:
- (A.sup.a+).sub.v (Mn.sup.b+)( M.sup.c+).sub.x P.sub.y O.sub.x
- where A is a templating agent selected from the group consisting of alkali metals, alkaline earth metals, hydronium ion, ammonium ion, organoammonium ions, silver, copper (II), zinc (II), nickel (II), mercury (II), cadmium (II), and mixtures thereof, "a" represents a weighted average valence of A and varies from 1.0 to 2.0, "v" is the mole ratio of A to Mn and varies from about 0.1 to about 5, "b" is the average valence of Mn and has a value of greater than 3 to about 4, M is a metal selected from the group consisting of Al, Fe.sup.3+, Ga, Sn.sup.4+, Ti, Sb.sup.5+, Ag, Zn, Cu, Ni, Cd, and mixtures thereof, "x" is the mole ratio of M to Mn and varies from 0 to about 3.0, "c" is the weighted average valence of M and varies from about 1.0 to about 5.0, "y" is the mole ratio of P to Mn and varies from about 0.10 to about 5.0 and "z" is the mole ratio of O to Mn and has a value determined by the equation
- z=1/2(a "v+b+x" c+5y).
Dependencies are inferred from the claim text.