Process for synthesizing perovskites using high energy milling
AssigneeUniversite Laval
InventorsSerge Kaliaguine, Andre Van Neste
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AssigneeUniversite Laval
InventorsSerge Kaliaguine, Andre Van Neste
Estimating the term…
Perovskite-type structure compounds having the general empirical formula ABO.sub.3 are prepared by a process comprising subjecting a mixture of starting powders formulated to contain the components represented by A and B in the formula to a high energy milling sufficient to induce chemical reaction of the components and thereby synthesize a mechanically-alloyed powder comprising the perovskite in the form of nanostructural particles. The process according to the present invention is simple, efficient, not expensive and does not require any heating step for producing a perovskite that may easily show a very high specific surface area. Another advantage is that the perovskite obtained according to the present invention also has a high density of lattice defects thereby showing a higher catalytic activity, a characteristic which is highly desirable in their eventual application as catalysts and electronic conductors.
A process for mechanosynthesizing a perovskite of the general formula ABO.sub.3, said process consisting essentially of the step of subjecting a mixture of starting powders formulated to contain separately the components represented by A and B in the formula to a high energy milling under an oxygen containing atmosphere, said high energy milling being sufficient to induce chemical reaction of the components and thereby mechanosynthesize said perovskite in the form of a nanostructural single phase perovskite.
A process for mechanosynthesizing a perovskite of the general formula ABO.sub.3, having a high BET specific surface area, said process consisting essentially of the steps of:
A perovskite having the formula LaCoO.sub.3 and a BET specific surface area of at least 20 m.sup.2 /g.
Dependencies are inferred from the claim text.