Polyhydric alcohol stabilized antiperspirant salt solutions
AssigneeThe Gillette Company
InventorYan-Fei Shen
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AssigneeThe Gillette Company
InventorYan-Fei Shen
Estimating the term…
The present invention relates to methods of making enhanced efficacy antiperspirant salts and particularly stabilized aqueous polyhydric alcohol solutions of such salts. One such method involves stabilizing an aqueous solution of an enhanced efficacy antiperspirant salt by adding an effective amount of a polyhydric alcohol having from 3 to 6 carbon atoms and from 3 to 6 hydroxyl groups. A second disclosed method involves preparing an enhanced efficacy aluminum antiperspirant salt by heating an aqueous solution of an aluminum antiperspirant salt in the presence of a polyhydric alcohol having from 3 to 6 carbon atoms and from 3 to 6 hydroxyl groups at a temperature of at least 50.degree. C. for a time sufficient to convert the salt to an enhanced salt. A third disclosed method is an improvement in the method of making an aluminum hydroxy halide or an aluminum hydroxy nitrate by reacting aluminum with an aqueous solution of aluminum halide or aluminum nitrate (or with aqueous hydrogen halide or nitric acid), wherein the improvement comprises including a polyhydric alcohol having from 3 to 6 carbon atoms and from 3 to 6 hydroxyl groups in the reaction mixture. Also disclosed are compositions produced by the foregoing methods.
A stabilized aqueous antiperspirant composition comprising, in percent by weight (USP), about 20 to 42% of an enhanced efficacy aluminum or aluminum-zirconium antiperspirant salt having an HPLC peak 4 to peak 3 area ratio of at least 0.5 with at least 70% of the aluminum contained in said peaks 3 and 4, about 25 to 60% water, and about 10 to 40% of a polyhydric alcohol having from 3 to 6 carbon atoms and from 3 to 6 hydroxyl groups.
A method of stabilizing an aqueous solution of an enhanced efficacy aluminum or aluminum-zirconium antiperspirant salt against rapid degradation of the HPLC peak 4 to peak 3 area ratio of said salt, wherein said salt has an HPLC peak 4 to peak 3 area ratio of at least 0.5 with at least 70% of the aluminum contained in said peaks 3 and 4, said method comprising adding to said aqueous enhanced efficacy antiperspirant salt solution an effective amount of a polyhydric alcohol having from 3 to 6 carbon atoms and from 3 to 6 hydroxyl groups to form a stabilized aqueous enhanced efficacy antiperspirant salt solution comprising about 20 to 42% of said antiperspirant salt, about 25 to 60% water, and about 10 to 40% of said polyhydric alcohol.
A method of preparing a stabilized aqueous enhanced efficacy aluminum antiperspirant salt solution which comprises heating an aqueous solution of an aluminum antiperspirant salt in the presence of a polyhydric alcohol having from 4 to 6 carbon atoms and from 4 to 6 hydroxyl groups at a temperature of at least 50.degree. C. for a time sufficient to convert the aluminum antiperspirant salt to an enhanced efficacy aluminum antiperspirant salt having an HPLC peak 4 to peak 3 area ratio of at least 0.5 with at least 70% of the aluminum contained in said peaks 3 and 4.
A stabilized aqueous antiperspirant composition comprising, in percent by weight (USP), about 18 to 45% of an enhanced efficacy aluminum or aluminum-zirconium antiperspirant salt having an HPLC peak 4 to peak 3 area ratio of at least 0.5 with at least 70% of the aluminum contained in said peaks 3 and 4, about 20 to 70% water, and about 5 to 60% of a polyhydric alcohol having from 4 to 6 carbon atoms and from 4 to 6 hydroxyl groups.
A method of stabilizing an aqueous solution of an enhanced efficacy aluminum or aluminum-zirconium antiperspirant salt against rapid degradation of the HPLC peak 4 to peak 3 area ratio of said salt, wherein said salt has an HPLC peak 4 to peak 3 area ratio of at least 0.5 with at least 70% of the aluminum contained in said peaks 3 and 4, said method comprising adding to said aqueous enhanced efficacy antiperspirant salt solution an effective amount of a polyhydric alcohol having from 4 to 6 carbon atoms and from 4 to 6 hydroxyl groups to form a stabilized aqueous enhanced efficacy antiperspirant salt solution comprising about 18 to 45% of said antiperspirant salt, about 25 to 70% water, and about 5 to 60% of said polyhydric alcohol.
Dependencies are inferred from the claim text.