Heat sensitive color developing material and heat sensitive element using the same
AssigneeMatsushita Electric Industrial Co., Ltd.
InventorsIchiro Tanahashi, Takao Tohda, Hiroshi Kanno
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Abstract
A thermal-sensitive color developing material containing metal particles and a matrix substance where the size of the metal particles irreversibly increase at room temperature due to cohesion, and a thermal-sensitive element using the thermal-sensitive color developing material are disclosed. The thermal-sensitive color developing material irreversibly develops a color at a temperature of room temperature or higher.
Claims51
A thermal-sensitive color developing material comprising metal particles and a matrix substance, wherein the size of the metal particles irreversibly increases at room temperature due to cohesion, and wherein the metal particles are formed from a mixture of a metal ion and an .alpha.-hydrogen-containing, alcohol upon irradiation with light, and the metal ion is at least one member selected from the group consisting of gold, platinum, silver, copper, tin, rhodium, palladium and iridium.
A thermal-sensitive element comprising a base substrate and a thermal sensitive color developing material held by the base substrate, wherein:
- the thermal-sensitive color developing material contains metal particles a d a matrix substance;
- the size of the metal particles are irreversibly increased at room temperature due to cohesion;
- and
- the metal particles are formed from a mixture of a metal ion and an .alpha.-hydrogen-containing alcohol upon irradiation with light, and the metal ion is at least one member selected from the group consisting of gold, platinum, silver, copper, tin, rhodium, palladium and iridium.
A thermal-sensitive element comprising a base substrate containing metal particles, wherein the size of the metal particles irreversibly increases at room temperature due to cohesion and
- wherein the metal particles are formed from a mixture of a metal ion and an .alpha.-hydrogen-containing alcohol upon irradiation with light, and the metal ion is at least one member selected from the group consisting of gold, platinum, silver, copper, tin, rhodium, palladium and iridium.
A method for producing a thermal-sensitive color developing material, comprising the steps of:
- preparing a mixture containing metal ion, an .alpha.-hydrogen-containing alcohol and a matrix-forming material;
- and
- irradiating the mixture with light,
- wherein the metal ion is at least one member selected from the group consisting of gold, platinum, silver, copper, tin, rhodium, palladium and iridium.
A method for producing a thermal-sensitive element including a base substrate and a thermal-sensitive color developing material held by the base substrate, comprising the steps of:
- preparing a mixture containing metal ion, an .alpha.-hydrogen-containing alcohol and a matrix-forming material;
- making the mixture held by the base substrate;
- and
- irradiating the mixture held by the base substrate with light so as to form the thermal-sensitive color developing material,
- wherein the metal ion is at least one member selected from the group consisting of gold, platinum, silver, copper, tin, rhodium, palladium and iridium.
A method for producing a thermal-sensitive element including a base substrate containing metal particles, comprising the steps of:
- preparing a mixture containing metal ion and an .alpha.-hydrogen-containing alcohol;
- impregnating the mixture into the base substrate;
- and
- irradiating the mixture impregnated in the base substrate with light so as to form the metal particles,
- wherein the metal ion is at least one member selected from the group consisting of gold, platinum, silver, copper, tin, rhodium, palladium and iridium.
A composition comprising metal ion, an .alpha.-hydrogen-containing alcohol and a matrix substance, wherein the metal ion and the .alpha.-hydrogen-containing alcohol are reactive together upon irradiation with light, forming metal particles which irreversibly increase in size at room temperature due to cohesion, and wherein the metal ion is at least one member selected from the group consisting of gold, platinum, silver, copper, tin, rhodium, palladium and iridium.
Dependencies are inferred from the claim text.